CdS/Ag2S nanocomposites photocatalyst with enhanced visible light photocatalysis activity

被引:35
作者
Wang, Chuang [1 ]
Zhai, Jiali [1 ]
Jiang, Huan [1 ]
Liu, Dechen [1 ]
Zhang, Lei [2 ]
机构
[1] Jilin Police Coll, Jilin Engn Res Ctr Forens Sci, Dept Forens Sci, 1399 Boshuo Rd, Changchun 130102, Jilin, Peoples R China
[2] Hebei Agr Univ, Coll Urban & Rural Construct, Baoding 071001, Peoples R China
基金
中国国家自然科学基金;
关键词
CdS/Ag2S; Photocatalysis; Interface; Charge separation; Z-SCHEME PHOTOCATALYST; BIOI MICROSPHERES; FACILE SYNTHESIS; METHYLENE-BLUE; HYDROGEN; NANOPARTICLES; DEGRADATION; OXIDE; HETEROSTRUCTURES; NANOSHEETS;
D O I
10.1016/j.solidstatesciences.2019.106020
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
To design efficient photocatalysis system, ultrafast photogenerated charge recombination in photocatalysts should be suppressed. Herein, CdS/Ag2S composites were prepared via in situ ion exchange method. The transmission electron microscopy (TEM) results showed that a heterojunction interface between CdS and Ag2S. The UV-vis diffuse reflection spectra (DRS) revealed that the as-prepared CdS/Ag2S composites owned more intensive absorption in the visible light range compared with pure CdS nanorods (NRs). These characteristic structural and optical properties endow CdS/Ag2S composites with enhanced photocatalytic activity. The MO degradation rate reached 93.0% within 25 min under visible light irradiation, the degradation rate of MO was 5 times higher than that of pure CdS NRs. The enhanced photocatalysis performance is mainly ascribed to the interface between CdS and Ag2S, which will lead to an effective photogenerated charge separation in the composite photocatalyst.
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页数:9
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