Insights into the activity, selectivity and stability of heterogeneous catalysts in the continuous flow hydroconversion of furfural

被引：45

作者：

Garcia-Olmo, Antonio J. ^{[1
]}

Yepez, Alfonso ^{[1
]}

Balu, Alina M. ^{[1
]}

Romero, Antonio A. ^{[1
]}

Li, Yingwei ^{[2
]}

Luque, Rafael ^{[1
]}

机构：

[1] Univ Cordoba, Dept Quim Organ, Campus Rabanales,Edificio Marie Curie C-3, E-14014 Cordoba, Spain

[2] S China Univ Technol, Sch Chem & Chem Engn, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2016年 / 6卷 / 13期

关键词：

MILD CONDITIONS; BIOMASS; HYDROGENATION; CONVERSION; CHEMICALS; FUELS; METAL; 2-METHYLFURAN; ACID; CYCLOPENTANONE;

D O I：

10.1039/c6cy00249h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The continuous flow hydroconversion of furfural to a range of furanic derivatives was carried out using a range of metal-containing heterogeneous catalysts in order to provide insights into the reaction pathways for the hydrogenation of furfural. Most of the catalysts used provided excellent furfural conversion (> 60%) and varying selectivities to products at mild temperatures (90 degrees C), including furfuryl alcohol (FA), 2-methylfuran (2-MF), 2-methyltetrahydrofuran (2-MTHF) and furanic intermediates, depending on the flow conditions and the investigated catalyst.

引用

收藏

页码：4705 / 4711

页数：7

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