Infrared study of crotonaldehyde and CO adsorption on a Pt/TiO2 catalyst

被引：45

作者：

Coloma, F ^{[1
]}

Coronado, JM ^{[1
]}

Rochester, CH ^{[1
]}

Anderson, JA ^{[1
]}

机构：

[1] Univ Dundee, Dept Chem, Dundee DD1 4HN, Scotland

来源：

CATALYSIS LETTERS | 1998年 / 51卷 / 3-4期

关键词：

FTIR; Pt/TiO2; crotonaldehyde hydrogenation; CO adsorption;

D O I：

10.1023/A:1019069925240

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A Pt/TiO2 catalyst has been subjected to reduction in hydrogen at 473, 573 and 773 K and the various degrees of metal-support interaction (SMSI) confirmed by means of CO and H-2 chemisorption, FTIR of CO and the hydrogenation of crotonaldehyde. Coadsorption of CO and crotonaldehyde were performed to identify the preferred adsorption site and mode of adsorption of the unsaturated aldehyde. Results which appear to suggest shifts to lower frequencies of bands due to adsorbed carbonyls are not due to electronic effects induced by coadsorption, but rather indicate displacement of CO from the weaker bonding sites which eliminate dipole coupling effects between different carbonyl clusters, and consequently removes intensity transfer phenomena leading to enhancement in intensity at lower frequencies.

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页码：155 / 162

页数：8

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