Dye-sensitized solar cells with TiO2 nanocrystalline films prepared by conventional and rapid thermal annealing processes

被引:16
作者
Kao, M. C. [1 ]
Chen, H. Z. [1 ]
Young, S. L. [1 ]
机构
[1] Hsiuping Inst Technol, Dept Elect Engn, Taichung, Taiwan
关键词
Titanium oxide; Nanostructures; Rapid thermal annealing; Dye-sensitized solar cells; TITANIUM;
D O I
10.1016/j.tsf.2010.12.032
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Titanium oxide (TiO2) thin films are prepared by the sol-gel method and annealed at 600 degrees C by conventional (CTA) and rapid thermal annealing (RTA) processes on fluorine-doped tin oxide-coated glass substrates for application as the work electrode for the dye-sensitized solar cells (DSSC). TiO2 thin films are crystallized using a conventional furnace and the proposed RTA process at annealing rates of 5 degrees Cmin(-1) and 600 degrees Cmin(-1), respectively. The TiO2 thin films are characterized by X-ray diffraction, scanning electron microscopy and Brunauer-Emmett-Teller analysis. Based on the results, the TiO2 films crystallized by RTA show better crystallization, higher porosity and larger surface area than those of CFA. The short-circuit photocurrent and open-circuit voltage values increased from 5.2 mAcm(-2) and 0.6 V for the DSSC with the CTA-derived TiO2 films to 8.3 mAcm(-2) and 0.68 V. respectively, for the DSSC containing RTA-derived TiO2 films. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:3268 / 3271
页数:4
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