Shape Induced Symmetry in Self-Assembled Mesocrystals of Iron Oxide Nanocubes

被引:134
作者
Disch, Sabrina [1 ,2 ]
Wetterskog, Erik [3 ]
Hermann, Raphael P. [1 ,2 ,4 ]
Salazar-Alvarez, German [3 ]
Busch, Peter [1 ,2 ]
Brueckel, Thomas [1 ,2 ]
Bergstroem, Lennart [3 ]
Kamali, Saeed [5 ]
机构
[1] Forschungszentrum Julich, Julich Ctr Neutron Sci JCNS, D-52425 Julich, Germany
[2] Forschungszentrum Julich, JARA FIT, Peter Grunberg Inst PGI, D-52425 Julich, Germany
[3] Stockholm Univ, Arrhenius Lab, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden
[4] Univ Liege, Fac Sci, B-4000 Liege, Belgium
[5] Japan Synchrotron Radiat Res Inst JASRI, Sayo, Hyogo 6795198, Japan
基金
瑞典研究理事会;
关键词
Nanoparticles; self-assembly; structure; GISAXS; iron oxide; particle interactions; BINARY NANOPARTICLE SUPERLATTICES; 3-DIMENSIONAL SUPERLATTICES; MONODISPERSE NANOCRYSTALS; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; ELECTRIC-FIELD;
D O I
10.1021/nl200126v
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Grazing incidence small-angle scattering,and electron microscopy have been used to show for the first time that nonspherical nanoparticles can assemble into highly ordered body-centered tetragonal mesocrystals. Energy models accounting for the directionality and magnitude of the van der Waals and dipolar interactions as a function of the degree of truncation of the nanocubes illustrated the importance of the directional dipolar forces for the formation of the initial nanocube clusters and the dominance of the van der Waals multibody interactions in the dense packed arrays.
引用
收藏
页码:1651 / 1656
页数:6
相关论文
共 36 条
[1]   Magnetic field-induced assembly of oriented superlattices from maghemite nanocubes [J].
Ahniyaz, Anwar ;
Sakamoto, Yasuhiro ;
Bergstrom, Lennart .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2007, 104 (45) :17570-17574
[2]  
[Anonymous], ENCY COMPLEXITY SYST
[3]   ORDERED AGGREGATES OF ULTRAFINE IRON-OXIDE PARTICLES - SUPER CRYSTALS [J].
BENTZON, MD ;
VANWONTERGHEM, J ;
MORUP, S ;
THOLEN, A ;
KOCH, CJW .
PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1989, 60 (02) :169-178
[4]   Nanoscale Forces and Their Uses in Self-Assembly [J].
Bishop, Kyle J. M. ;
Wilmer, Christopher E. ;
Soh, Siowling ;
Grzybowski, Bartosz A. .
SMALL, 2009, 5 (14) :1600-1630
[5]   Grazing-incidence small-angle X-ray scattering from thin polymer films with lamellar structures-the scattering cross section in the distorted-wave Born approximation [J].
Busch, P. ;
Rauscher, M. ;
Smilgies, D. -M. ;
Posselt, D. ;
Papadakis, C. M. .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2006, 39 :433-442
[6]   Collective Dipolar Interactions in Self-Assembled Magnetic Binary Nanocrystal Superlattice Membranes [J].
Chen, Jun ;
Dong, Angang ;
Cai, Jing ;
Ye, Xingchen ;
Kang, Yijin ;
Kikkawa, James M. ;
Murray, Christopher B. .
NANO LETTERS, 2010, 10 (12) :5103-5108
[7]   Shape evolution of single-crystalline iron oxide nanocrystals [J].
Cheon, JW ;
Kang, NJ ;
Lee, SM ;
Lee, JH ;
Yoon, JH ;
Oh, SJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (07) :1950-1951
[8]   Shape-Controlled Platinum Nanocubes and Their Assembly into Two-Dimensional and Three-Dimensional Superlattices [J].
Demortiere, A. ;
Launois, P. ;
Goubet, N. ;
Albouy, P. -A. ;
Petit, C. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (46) :14583-14592
[9]   Anisotropy of building blocks and their assembly into complex structures [J].
Glotzer, Sharon C. ;
Solomon, Michael J. .
NATURE MATERIALS, 2007, 6 (08) :557-562
[10]   Phase diagram for stimulus-responsive materials containing dipolar colloidal particles [J].
Goyal, Amit ;
Hall, Carol K. ;
Velev, Orlin D. .
PHYSICAL REVIEW E, 2008, 77 (03)