Carbon nanofilm with a new structure and property

被引:101
作者
Horiuchi, S
Gotou, T
Fuijwara, M
Sotoaka, R
Hirata, M
Kimoto, K
Asaka, T
Yokosawa, T
Matsui, Y
Watanabe, K
Sekita, M
机构
[1] Mitsubishi Gas Chem Co Inc, Corp Res Lab, Tsukuba, Ibaraki 3004247, Japan
[2] Natl Inst Mat Sci, Adv Mat Lab, Tsukuba, Ibaraki 3050044, Japan
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS | 2003年 / 42卷 / 9AB期
关键词
carbon nanofilm; HRTEM; ED; structure analysis; thickness; stacking sequence; EELS; O/C; semiconductor;
D O I
10.1143/JJAP.42.L1073
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have prepared a carbon film of nanometer thickness, which is called here a carbon nanofilm (CNF), starting from the oxidation of graphite. The structure and thickness of the CNF are determined by high-resolution transmission electron microscopy and electron diffraction. The structure is of a new type (S.G.: P3), in which carbon six-membered-ring planes are stacked with the sequence of... AA.... According to electron energy loss spectroscopy, a substantial amount of oxygen is detected but the molar ratio of oxygen to carbon is possibly decreased to less than 0.1. The CNF changes from an insulator to a semiconductor when reduced on heating at 250degreesC.
引用
收藏
页码:L1073 / L1076
页数:4
相关论文
共 12 条
[1]  
BOEHM HP, 1962, Z NATURFORSCH PT B, VB 17, P150
[2]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[3]   CONFORMATION OF GRAPHITE OXIDE MEMBRANES IN SOLUTION [J].
HWA, T ;
KOKUFUTA, E ;
TANAKA, T .
PHYSICAL REVIEW A, 1991, 44 (04) :R2235-R2238
[4]   Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations [J].
Kovtyukhova, NI ;
Ollivier, PJ ;
Martin, BR ;
Mallouk, TE ;
Chizhik, SA ;
Buzaneva, EV ;
Gorchinskiy, AD .
CHEMISTRY OF MATERIALS, 1999, 11 (03) :771-778
[5]   Structure of graphite oxide revisited [J].
Lerf, A ;
He, HY ;
Forster, M ;
Klinowski, J .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (23) :4477-4482
[6]   FTIR AND C-13 NMR-STUDY OF GRAPHITE OXIDE [J].
MERMOUX, M ;
CHABRE, Y ;
ROUSSEAU, A .
CARBON, 1991, 29 (03) :469-474
[7]   Local structural order in electron-irradiated graphite studied by high-resolution high-voltage electron microscopy [J].
Muto, SE ;
Horiuchi, S ;
Tanabe, T .
JOURNAL OF ELECTRON MICROSCOPY, 1999, 48 (06) :767-776
[8]   FORMATION PROCESS AND STRUCTURE OF GRAPHITE OXIDE [J].
NAKAJIMA, T ;
MATSUO, Y .
CARBON, 1994, 32 (03) :469-475
[9]   A NEW STRUCTURE MODEL OF GRAPHITE OXIDE [J].
NAKAJIMA, T ;
MABUCHI, A ;
HAGIWARA, R .
CARBON, 1988, 26 (03) :357-361
[10]   ORDER-DISORDER TRANSFORMATIONS IN GRAPHITE NITRATES [J].
NIXON, DE ;
PARRY, GS ;
UBBELOHDE, AR .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1966, 291 (1426) :324-+