Mechanical properties and crystallization behavior of three kinds of straws/nylon 6 composites

被引:10
|
作者
Huang, Zhiliang [1 ,2 ]
Yin, Qianjuan [1 ]
Wang, Qianwen [1 ]
Wang, Pinghua [3 ]
Liu, Tingguo [1 ]
Qian, Liwu [1 ]
机构
[1] Chizhou Univ, Dept Chem Mat Engn, Chizhou 247000, Peoples R China
[2] Huainan Normal Univ, Huainan Engn Res Ctr Fuel Cells, Anhui Key Lab Low Temp Cofired Mat, Huainan, Peoples R China
[3] Hefei Univ Technol, Sch Chem Engn, Hefei 230000, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
Nylon; 6; Wheat straw; Maize straw; Rice straw; PINEAPPLE LEAF FIBER; SURFACE-TREATMENTS; REINFORCEMENT; NYLON-6; PERFORMANCE;
D O I
10.1016/j.ijbiomac.2017.05.121
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
After alkali treatment, wheat straw, maize straw and rice straw were mixed with a mixture of nylon 6 (PA6) and prepared into composites using the melt blending method. The mechanical properties and crystallization behavior of three kinds of straw fiber/PA6 composites were studied using tensile and impact tests, differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The results showed that increasing of the three kinds of straw fibers initially increased the tensile strength of the composites and then decreased, and that the tensile strength reached a maximum value when the wheat straw fiber content was 10%, which was 56.9% higher than that of the pure PA6. The impact strength of the composites initially decreased and then increased, with the maximum impact obtained for the composites with the wheat straw fiber content of 10%, which was 39.2% higher than that of the pure PA6. The introduction of the three kinds of straw fiber also induced the formation of a crystal formed in the PA6. With the increase of the straw fiber content, the grain size of the composite increased continuously, the crystallization temperature (Tc) decreased, the melting temperature (Tm) and crystalline changed slightly, and the maximum degree of crystallinity was obtained when the wheat straw fiber content was 10%. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:663 / 668
页数:6
相关论文
共 50 条
  • [41] Nonisothermal Crystallization and Melting Behavior of in-situ Polymerized Nylon 11/Nylon 66 Composites
    Jiang, Jinxing
    Guo, Qiwen
    Cai, Yanli
    POLYMERS & POLYMER COMPOSITES, 2011, 19 (2-3): : 55 - 67
  • [42] MECHANICAL-PROPERTIES AND FRACTURE BEHAVIOR OF UNIDIRECTIONALLY REINFORCED NYLON-6
    BESSELL, TJ
    SHORTALL, JB
    JOURNAL OF MATERIALS SCIENCE, 1977, 12 (02) : 365 - 372
  • [43] Morphology and mechanical properties of multiwalled carbon nanotubes reinforced nylon-6 composites
    Liu, TX
    Phang, IY
    Shen, L
    Chow, SY
    Zhang, WD
    MACROMOLECULES, 2004, 37 (19) : 7214 - 7222
  • [44] Effects of zinc acetate and cucurbit[6]uril on PP composites: crystallization behavior, foaming performance and mechanical properties
    Zhou, Yuhui
    He, Li
    Gong, Wei
    E-POLYMERS, 2018, 18 (06): : 491 - 499
  • [45] Miscibility and mechanical properties of aryl-aliphatic polyamides nylon 6 molecular composites
    Wang, CH
    Chen, LW
    POLYMER BULLETIN, 1996, 37 (03) : 369 - 376
  • [46] The crystallization behavior of nylon 66/nano-SiO2 composites
    Hu, Xiuchi
    Wang, Xiaomei
    2013 INTERNATIONAL CONFERENCE ON MATERIALS FOR RENEWABLE ENERGY AND ENVIRONMENT (ICMREE), VOLS 1-3, 2013, : 585 - 588
  • [47] Morphology and Crystallization Behavior of Nylon 6-Clay/Neat Nylon 6 Bicomponent Nanocomposite Fibers
    Kazemi, Shahin
    Mojtahedi, Mohammad Reza Mohaddes
    Takarada, Wataru
    Kikutani, Takeshi
    JOURNAL OF APPLIED POLYMER SCIENCE, 2014, 131 (06)
  • [48] Effect of Carbon Fiber Orientation on the Physical Properties and Crystallization Behavior of Nylon 66/Carbon Filler Composites
    Kim, Jun Seok
    Kim, Yu Shin
    Kim, Youn Cheol
    POLYMER-KOREA, 2019, 43 (04) : 547 - 552
  • [49] Thermal conductivity behavior of SiC–Nylon 6,6 and hBN–Nylon 6,6 composites
    Seunggun Yu
    Do-Kyun Kim
    Cheolmin Park
    Soon Man Hong
    Chong Min Koo
    Research on Chemical Intermediates, 2014, 40 : 33 - 40
  • [50] Creep behavior of nylon-6 thermoplastic composites
    Liou, WJ
    Tseng, CI
    POLYMER COMPOSITES, 1997, 18 (04) : 492 - 499