Physical origin of the third order nonlinear optical response of orthogonal pyrrolo-tetrathiafulvalene derivatives

被引:70
作者
Iliopoulos, K. [1 ]
Czaplicki, R. [1 ]
El Ouazzani, H. [1 ]
Balandier, J. Y. [1 ]
Chas, M. [1 ]
Goeb, S. [1 ]
Salle, M. [1 ]
Gindre, D. [1 ]
Sahraoui, B. [1 ]
机构
[1] Univ Angers, CNRS UMR 6200, Inst Sci & Technol Mol Angers Moltech Anjou, F-49045 Angers, France
关键词
NUCLEAR CONTRIBUTIONS; SUBSTITUTED TETRATHIAFULVALENE;
D O I
10.1063/1.3482943
中图分类号
O59 [应用物理学];
学科分类号
摘要
We present the third order nonlinear optical study of tetrathiafulvalene-based molecular corners. Degenerate four-wave mixing measurements have been done to provide information about the magnitude and the origin of the nonlinearity, while the nonlinear absorption has been separately measured by performing "open aperture" Z-scan measurements. The response has been found to be strongly dependent upon the structure of the molecular corners. (C) 2010 American Institute of Physics. [doi:10.1063/1.3482943]
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页数:3
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