Nickel-Catalyzed Addition of C-C Bonds of Amides to Strained Alkenes: The 1,2-Carboaminocarbonylation Reaction

被引：25

作者：

Ito, Yuri ^{[1
]}

Nakatani, Syun ^{[1
]}

Shiraki, Ryota ^{[1
]}

Kodama, Takuya ^{[1
,2
]}

Tobisu, Mamoru ^{[1
,2
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Osaka Univ, Inst Open & Transdisciplinary Res Initiat ICS OTR, Innovat Catalysis Sci Div, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2022年 / 144卷 / 02期

关键词：

ACTIVATION;

D O I：

10.1021/jacs.1c09265

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C aryll-C(=O) bonds of aryl amides can be activated and added across alkenes with the aid of a nickel catalyst. This 1,2-carboaminocarbonylation reaction enables the dicarbofunctionalization of alkenes with an atom economy of 100%.

引用

页码：662 / 666

页数：5

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