Nickel-Catalyzed Addition of C-C Bonds of Amides to Strained Alkenes: The 1,2-Carboaminocarbonylation Reaction

被引：25
|
作者：
Ito, Yuri [1 ]
Nakatani, Syun [1 ]
Shiraki, Ryota [1 ]
Kodama, Takuya [1 ,2 ]
Tobisu, Mamoru [1 ,2 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[2] Osaka Univ, Inst Open & Transdisciplinary Res Initiat ICS OTR, Innovat Catalysis Sci Div, Suita, Osaka 5650871, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2022年 / 144卷 / 02期
关键词：
ACTIVATION;
D O I：
10.1021/jacs.1c09265
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
C aryll-C(=O) bonds of aryl amides can be activated and added across alkenes with the aid of a nickel catalyst. This 1,2-carboaminocarbonylation reaction enables the dicarbofunctionalization of alkenes with an atom economy of 100%.
引用
收藏
页码：662 / 666
页数：5
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