Exfoliated graphitic carbon dots: Application in heavy metal ion sensing

被引:25
作者
Ansi, V. A. [1 ]
Renuka, N. K. [1 ]
机构
[1] Univ Calicut, Dept Chem, Calicut 673635, Kerala, India
关键词
Highly Exfoliated Graphitic Carbon dots; Hg (II) sensing; Excitation energy transfer; GREEN SYNTHESIS; COLORIMETRIC DETECTION; GOLD NANOPARTICLES; ENERGY-TRANSFER; AQUEOUS-MEDIA; MERCURY(II); POLYMER; SENSOR; WATER;
D O I
10.1016/j.jlumin.2018.09.061
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Highly Exfoliated Graphitic Carbon dot (HEG carbon dot) is reported herein, exploiting commercially available table sugar (sucrose) as a green precursor. An amorphous carbon matrix, made of 7-8 graphenic units constitutes the HEG carbon dot core. This system exhibits excitation energy transfer with the Xanthene dye, Rhodamine-B, which is expressed as a noticeable enhancement in the luminescence of the dye. Metal ion assisted hindrance in FRET is noticed in presence of Hg (II) ion, which paves way to the fabrication of an efficient Hg (II) ion sensing tool. The system exhibits high selectivity and sensitivity with Limit of Detection 98 pM.
引用
收藏
页码:467 / 474
页数:8
相关论文
共 35 条
[11]   Technical report: Mercury in the environment: Implications for pediatricians [J].
Goldman, LR ;
Shannon, MW .
PEDIATRICS, 2001, 108 (01) :197-205
[12]   Is low-level environmental mercury exposure of concern to human health? [J].
Holmes, P. ;
James, K. A. F. ;
Levy, L. S. .
SCIENCE OF THE TOTAL ENVIRONMENT, 2009, 408 (02) :171-182
[13]   Graphene synthesis via hydrogen induced low temperature exfoliation of graphite oxide [J].
Kaniyoor, Adarsh ;
Baby, Tessy Theres ;
Ramaprabhu, Sundara .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (39) :8467-8469
[14]   Visual sensing of Hg2+ using unmodified Au@Ag core–shell nanoparticles [J].
Li L. ;
Feng D. ;
Fang X. ;
Han X. ;
Zhang Y. .
Journal of Nanostructure in Chemistry, 2014, 4 (3)
[15]   Highly Sensitive, Colorimetric Detection of Mercury(II) in Aqueous Media by Quaternary Ammonium Group-Capped Gold Nanoparticles at Room Temperature [J].
Liu, Dingbin ;
Qu, Weisi ;
Chen, Wenwen ;
Zhang, Wie ;
Wang, Zhuo ;
Jiang, Xingyu .
ANALYTICAL CHEMISTRY, 2010, 82 (23) :9606-9610
[16]  
Liu XJ, 2013, BIORESOURCES, V8, P2537
[17]   Economical, Green Synthesis of Fluorescent Carbon Nanoparticles and Their Use as Probes for Sensitive and Selective Detection of Mercury(II) Ions [J].
Lu, Wenbo ;
Qin, Xiaoyun ;
Liu, Sen ;
Chang, Guohui ;
Zhang, Yingwei ;
Luo, Yonglan ;
Asiri, Abdullah M. ;
Al-Youbi, Abdulrahman O. ;
Sun, Xuping .
ANALYTICAL CHEMISTRY, 2012, 84 (12) :5351-5357
[18]   Colorimetric detection of mercury(II) in aqueous media with high selectivity using calixarene functionalized gold nanoparticles [J].
Maity, Debdeep ;
Kumar, Anshu ;
Gunupuru, Ravi ;
Paul, Parimal .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2014, 455 :122-128
[19]   Fluorescent probe: complexation of Fe3+ with the myo-inositol 1,2,3-trisphosphate motif [J].
Mansell, David ;
Rattray, Nicholas ;
Etchells, Laura L. ;
Schwalbe, Carl H. ;
Blake, Alexander J. ;
Bichenkova, Elena V. ;
Bryce, Richard A. ;
Barker, Christopher J. ;
Diaz, Alvaro ;
Kremer, Carlos ;
Freeman, Sally .
CHEMICAL COMMUNICATIONS, 2008, (41) :5161-5163
[20]   One-pot green synthesis of carbon dots by using Saccharum officinarum juice for fluorescent imaging of bacteria (Escherichia coli) and yeast (Saccharomyces cerevisiae) cells [J].
Mehta, Vaibhavkumar N. ;
Jha, Sanjay ;
Kailasa, Suresh Kumar .
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2014, 38 :20-27