Synthesis of anhydrous yttrium and rare earth vanadium oxides from aqueous solution

被引：4

作者：

Jang, Meehae ^{[1
]}

Doxsee, Kenneth M. ^{[1
]}

机构：

[1] Univ Oregon, Dept Chem, Eugene, OR 97403 USA

来源：

CRYSTENGCOMM | 2011年 / 13卷 / 04期

关键词：

ND-YVO4 MICROCHIP LASERS; SOLID-STATE MATERIALS; CRYSTALLIZATION; VANADATES; ND; ORTHOVANADATE; YVO4EU3+; YVO4-EU; GROWTH;

D O I：

10.1039/c0ce00590h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Simple salt metathesis reactions from aqueous solutions of soluble precursor salts-Na3VO4 and LnX(3) (Ln = Y, La, Ce, Nd, Gd, Dy; X = Cl, NO3, CH3CO2) afford anhydrous yttrium and rare earth orthovanadates. The morphology of the resulting orthovanadates may be modified through variation of the crystallization configuration (test tube vs. u-tube), medium (aqueous, nonaqueous, gel), and reaction conditions (inclusion of chelating agents).

引用

页码：1210 / 1214

页数：5

共 42 条

[1] A review of the low temperature properties of the rare earth vanadates [J].