Ionic liquid-supported TEMPO as catalyst in the oxidation of alcohols to aldehydes and ketones

被引：50
|
作者：
Fall, Alioune [2 ]
Sene, Massene [2 ]
Gaye, Mohamed [1 ]
Gomez, Generosa [2 ]
Fall, Yagamare [2 ]
机构：
[1] Univ Cheikh Anta Diop Dakar, Chim Inorgan Lab, Dept Chim, Fac Sci & Tech, Dakar, Senegal
[2] Univ Vigo, Fac Ciencias, Dept Quim Organ, Vigo 36200, Spain
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 34期
关键词：
Oxidation reaction; Ionic liquids; Click chemistry; Green chemistry; SELECTIVE OXIDATION; SECONDARY ALCOHOLS; CARBOXYLIC-ACIDS; TRANSITION-METAL; AZIDE-ALKYNE; EFFICIENT; SALTS; OXIDANT;
D O I：
10.1016/j.tetlet.2010.06.086
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We describe an efficient synthesis of an ionic liquid-supported TEMPO which was used for the oxidation of alcohols to aldehydes and ketones. The predictable solubility of ionic liquids allows an easy separation of the oxidation products from reagents. Furthermore, the oxidation can be carried out using an ionic liquid as the solvent instead of dichloromethane; and the IL-supported TEMPO can be recycled and used several times without the loss of efficiency. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4501 / 4504
页数：4
相关论文
共 50 条
  • [21] Ionic TEMPO in Ionic Liquids: Specific Promotion of the Aerobic Oxidation of Alcohols
    Hirashita, Tsunehisa
    Nakanishi, Makoto
    Uchida, Tomoya
    Yamamoto, Masakazu
    Araki, Shuki
    Arends, Isabel W. C. E.
    Sheldon, Roger A.
    CHEMCATCHEM, 2016, 8 (16) : 2704 - 2709
  • [22] Synthetic utility of iodic acid in the oxidation of benzylic alcohols to aromatic aldehydes and ketones
    Imai, Sho
    Togo, Hideo
    TETRAHEDRON, 2016, 72 (44) : 6948 - 6954
  • [23] Selective oxidation of alcohols to aldehydes using inorganic-organic hybrid catalyst based on zinc substituted polyoxometalate and ionic liquid
    Nadealian, Zahra
    Mirkhani, Valiollah
    Yadollahi, Bahram
    Moghadam, Majid
    Tangestaninejad, Shahram
    Mohammadpoor-Baltork, Iraj
    JOURNAL OF COORDINATION CHEMISTRY, 2012, 65 (06) : 1071 - 1081
  • [24] Superparamagnetic core-shell radical polymer brush as efficient catalyst for oxidation of alcohols to aldehydes and ketones
    Yang, Jian-Jhe
    Li, Chia-Chen
    Yang, Yi-Fei
    Wang, Chan-Yang
    Lin, Chun-Hao
    Lee, Jyh-Tsung
    RSC ADVANCES, 2016, 6 (68) : 63472 - 63476
  • [25] Zirconia-Supported Ruthenium Catalyst for Efficient Aerobic Oxidation of Alcohols to Aldehydes
    Kim, Yo-Han
    Hwang, Seung-Kyu
    Kim, Jung Won
    Lee, Yoon-Sik
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (31) : 12548 - 12552
  • [26] Palladium Supported on Magnetic Core-Shell Nanoparticles: An Efficient and Reusable Catalyst for the Oxidation of Alcohols into Aldehydes and Ketones by Molecular Oxygen
    Zhang, Lei
    Li, Pinhua
    Yang, Jin
    Wang, Min
    Wang, Lei
    CHEMPLUSCHEM, 2014, 79 (02): : 217 - 222
  • [27] Synthetic utilities of ionic liquid-supported NHPI complex
    Koguchi, S
    Kitazume, T
    TETRAHEDRON LETTERS, 2006, 47 (16) : 2797 - 2801
  • [28] Development of a General and Practical Iron Nitrate/TEMPO-Catalyzed Aerobic Oxidation of Alcohols to Aldehydes/Ketones: Catalysis with Table Salt
    Ma, Shengming
    Liu, Jinxian
    Li, Suhua
    Chen, Bo
    Cheng, Jiajia
    Kuang, Jinqiang
    Liu, Yu
    Wan, Baoqiang
    Wang, Yuli
    Ye, Juntao
    Yu, Qiong
    Yuan, Weiming
    Yu, Shichao
    ADVANCED SYNTHESIS & CATALYSIS, 2011, 353 (06) : 1005 - 1017
  • [29] A mechanistic glimpse into the oxidation of alcohols using TEMPO/NOx catalytic systems: towards a greener bifunctional catalyst
    Ionita, Petre
    RSC ADVANCES, 2013, 3 (44) : 21218 - 21221
  • [30] Heteropoly acid-based supported ionic liquid-phase catalyst for the selective oxidation of alcohols
    Bordoloi, Ankur
    Sahoo, Suman
    Lefebvre, F.
    Halligudi, S. B.
    JOURNAL OF CATALYSIS, 2008, 259 (02) : 232 - 239
12345