Ion pair receptors

被引:428
作者
Kim, Sung Kuk [1 ]
Sessler, Jonathan L. [1 ,2 ]
机构
[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA
[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
基金
美国国家卫生研究院;
关键词
CROWN-ETHER; MOLECULAR RECOGNITION; ANION RECOGNITION; HETERODITOPIC RECEPTORS; COOPERATIVE BINDING; SIMULTANEOUS COMPLEXATION; SELECTIVE RECOGNITION; DITOPIC COMPLEXATION; RHENIUM(I) BIPYRIDYL; QUATERNARY AMMONIUM;
D O I
10.1039/c002694h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Compared with simple ion receptors, which are able to bind either a cation or an anion, ion pair receptors bearing both a cation and an anion recognition site offer the promise of binding ion pairs or pairs of ions strongly as the result of direct or indirect cooperative interactions between co-bound ions. This critical review focuses on the recent progress in the design of ion pair receptors and summarizes the various binding modes that have been used to accommodate ion pairs (110 references).
引用
收藏
页码:3784 / 3809
页数:26
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