Plasticizer for poly(vinyl chloride) from cardanol as a renewable resource material

被引：189

作者：

Greco, A. ^{[1
]}

Brunetti, D. ^{[1
]}

Renna, G. ^{[1
]}

Mele, G. ^{[1
]}

Maffezzoli, A. ^{[1
]}

机构：

[1] Univ Salento, Dept Engn Innovat, I-73100 Lecce, Italy

来源：

POLYMER DEGRADATION AND STABILITY | 2010年 / 95卷 / 11期

关键词：

PVC; Plasticizer; Renewable resource; Cardanol; SHELL LIQUID PREPOLYMER; INDUCED CROSS-LINKING; POLYMERIC PLASTICIZER; MECHANICAL-PROPERTIES; MELT RHEOLOGY; LINKED PVC; BLENDS; RUBBER; COMPATIBILITY; DEGRADATION;

D O I：

10.1016/j.polymdegradstab.2010.06.001

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The present work is aimed to the preliminary analysis of the applicability of cardanol derivatives as renewable plasticizers for soft PVC. Two different plasticizers were studied, obtained by esterification of the cardanol hydroxyl group (cardanol acetate) and further epoxidation of the side chain double bonds (epoxidated cardanol acetate). Differential Scanning Calorimetry (DSC) was used to study the miscibility between PVC and cardanol derived plasticizers. The miscibility was correlated to the chemical structure of plasticizer by means of the Hansen solubility parameter analysis. Results obtained indicated that esterification of cardanol yields a partial miscibility with PVC, whereas esterification and subsequent epoxidation yield a complete miscibility with PVC. Therefore cardanol acetate, obtained by solvent-free esterification of cardanol, was used as a secondary plasticizer of PVC. Mechanical and rheological analysis showed that the cardanol acetate can partially replace DEHP in PVC formulation. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：2169 / 2174

页数：6

共 32 条

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