New type of heterogeneous liquid-phase catalysts for hydrocarbons and their derivatives: Vanadium phosphates

被引：0
作者：
Zazhygalov, VO
Gasior, M
Vartikyan, L
Podobinski, J
Bacherykova, IV
机构：
[1] Natl Acad Sci Ukraine, LV Pisarzhevsky Phys Chem Inst, UA-252039 Kyiv, Ukraine
[2] Polish Acad Sci, Inst Catalysis & Surface Chem, PL-30239 Krakow, Poland
[3] Inst Phys Chem, Yerevan, Armenia
来源：
TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1998年 / 34卷 / 01期
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Activity of vanadium phosphates in the oxidation reactions of 10 hydrocarbons and their derivatives (benzene, phenol, toluene, naphthalene, naphthol, alpha-, beta-, gamma-methylpyridine, pyridine, cyclohexanol) with hydrogen peroxide has been studied for the first time. It has been established that catalytic activity and composition of the products depend on the nature of both vanadium phosphate phase and additives introduced in it. It has been shown that together with typical products of liquid-phase oxidation the proposed catalysts permit to obtain some new compounds.
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页码：43 / 46
页数：4
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