Synthesis of Planar Chiral Carbazole Derivatives Bearing a [2.2]Paracyclophane Skeleton

被引：16

作者：

Lennartz, Petra ^{[1
]}

Raabe, Gerhard ^{[1
]}

Bolm, Carsten ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany

来源：

ISRAEL JOURNAL OF CHEMISTRY | 2012年 / 52卷 / 1-2期

关键词：

carbazoles; cyclophanes; oxidative cyclization; palladium; planar chirality; ANILIDE ORTHO-ARYLATION; ARYL BOND FORMATION; C-H; ENANTIOSELECTIVE SYNTHESIS; IRIDIUM COMPLEXES; MACRO RINGS; PALLADIUM; LIGANDS; FUNCTIONALIZATION; 1,2-ADDITION;

D O I：

10.1002/ijch.201100070

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of planar chiral carbazoles bearing a [2.2]paracyclophane backbone is described. Starting from readily available 4-bromo[2.2]paracyclophane planar chiral carbazoles are obtained in a two-step synthesis by Pd-catalyzed C?N cross-coupling and subsequent oxidative cyclization.

引用

页码：171 / 179

页数：9

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