Electron-deficient [TiIV(salophen)(OTf)2]: A new and highly efficient catalyst for the acetylation of alcohols and phenols with acetic anhydride

被引：12

作者：

Yadegari, Maryam ^{[2
]}

Moghadam, Majid ^{[1
]}

Tangestaninejad, Shahram ^{[1
]}

Mirkhani, Valiollah ^{[1
]}

Mohammadpoor-Baltork, Iraj ^{[1
]}

机构：

[1] Univ Isfahan, Catalysis Div, Dept Chem, Esfahan 817467344, Iran

[2] Islamic Azad Univ, Sci & Res Branch, Dept Chem, Tehran, Iran

来源：

POLYHEDRON | 2011年 / 30卷 / 13期

关键词：

Titanium Schiff base; Protection; Acetic anhydride; Acetylation; Alcohol; Phenol; HIGH-VALENT METALLOPORPHYRIN; ALLYL VINYL ETHERS; REUSABLE CATALYST; ENANTIOSELECTIVE TRIMETHYLSILYLCYANATION; SELECTIVE ACETYLATION; VERSATILE CATALYST; TIN(IV) PORPHYRIN; ACID ANHYDRIDES; SILICA-GEL; ACYLATION;

D O I：

10.1016/j.poly.2011.06.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the present work, a highly efficient method for acetylation of alcohols and phenols with acetic anhydride catalyzed by high-valent (Ti-IV(salophen)(OTf)(2)] is reported. Under these conditions, primary, secondary and tertiary alcohols as well as phenols were acetylated with short reaction times and high yields. The catalyst was reused several times without loss of its catalytic activity. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：2237 / 2243

页数：7

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