Micellar RAFT/MADIX Polymerization

被引：10

作者：

Barthet, Cecile ^{[1
,3
]}

Wilson, James ^{[2
]}

Cadix, Arnaud ^{[2
]}

Destarac, Mathias ^{[1
]}

Chassenieux, Christophe ^{[3
]}

Harrisson, Simon ^{[1
]}

机构：

[1] Univ Paul Sabatier, Univ Toulouse, CNRS UMR 5623, Lab IMRCP, 118 Route Narbonne, F-31062 Toulouse 9, France

[2] Solvay Novecare, Res & Innovat Ctr Paris, F-93306 Aubervilliers, France

[3] Le Mans Univ, IMMM, UMR 6283, Ave Olivier Messiaen, F-72085 Le Mans 9, France

来源：

ACS MACRO LETTERS | 2017年 / 6卷 / 12期

关键词：

HYDROPHOBICALLY-MODIFIED POLYACRYLAMIDES; ASSOCIATING POLYACRYLAMIDES; MOLECULAR-WEIGHT; ACRYLAMIDE; POLYMERS; RHEOLOGY; BEHAVIOR; DESIGN;

D O I：

10.1021/acsmacrolett.7b00791

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We apply the RAFT/MADIX technique to the micellar copolymerization of acrylamide and 2-acrylamido-2-methylpropanesulfonic acid sodium salt with a hydrophobic monomer, 4-tert-butylstyrene. The resulting polymers have well-controlled molecular weight distributions. In the presence of sodium dodecyl sulfate, the polymerization is better controlled by an oligo-acrylamide chain transfer agent (PAm7-XA1) than by Rhodixan A1. The associative character of the polymer is maintained under RAFT polymerization conditions and chains can be extended to form block copolymers with associative segments.

引用

页码：1342 / 1346

页数：5

共 50 条

[1] Direct aqueous RAFT/MADIX polymerization of vinylphosphonic acid
Blidi, Issam
Geagea, Roland
Coutelier, Olivier
Violleau, Frederic
Destarac, Mathias
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
[2] Aqueous RAFT/MADIX polymerization: Pushing back the limits of control
Destarac, Mathias
Guinaudeau, Aymeric
Read, Emmanuelle
Coutelier, Olivier
Mazieres, Stephane
Wilson, David J.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
[3] Magnetic nanoparticles with chelating shells prepared by RAFT/MADIX polymerization
Markiewicz, Karolina H.
Zembko, Paula
Poltorak, Katarzyna
Misztalewska, Iwona
Wojtulewski, Slawomir
Majcher, Anna M.
Fornal, Emilia
Wilczewska, Agnieszka Z.
NEW JOURNAL OF CHEMISTRY, 2016, 40 (11) : 9223 - 9231
[4] Aqueous RAFT/MADIX Polymerization: Same Monomers, New Polymers?
Destarac, Mathias
Blidi, Issam
Coutelier, Olivier
Guinaudeau, Aymeric
Mazieres, Stephane
Van Gramberen, Eric
Wilson, James
PROGRESS IN CONTROLLED RADICAL POLYMERIZATION: MECHANISMS AND TECHNIQUES, 2012, 1100 : 259 - +
[5] Aqueous RAFT/MADIX polymerization: Same monomers, new polymers
Destarac, Mathias
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
[6] Influence of the chemical structure of MADIX agents on the RAFT polymerization of styrene
Adamy, M
van Herk, AM
Destarac, M
Monteiro, MJ
MACROMOLECULES, 2003, 36 (07) : 2293 - 2301
[7] Synthesis of poly(vinyl alcohol) combs via MADIX/RAFT polymerization
Bernard, J
Favier, A
Davis, TP
Barner-Kowollik, C
Stenzel, MH
POLYMER, 2006, 47 (04) : 1073 - 1080
[8] Aqueous RAFT/MADIX Polymerization of Vinylphosphonic Acid under Microwave Irradiation
Coutelier, Olivier
Blidi, Issam
Reynaud, Stephanie
Grassl, Bruno
Destarac, Mathias
CONTROLLED RADICAL POLYMERIZATION, VOL 1: MECHANISMS, 2015, 1187 : 283 - +
[9] Phosphonate-terminated poly(vinyl acetate) synthesized by RAFT/MADIX polymerization
Dufils, P-E.
David, G.
Boutevin, B.
Woodward, G.
Otter, G.
Guinaudeau, A.
Mazieres, S.
Destarac, M.
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (10) : 1997 - 2007
[10] RAFT/MADIX (co)polymerization of vinyl trifluoroacetate: a means to many ends
Girard, Etienne
Liu, Xuan
Marty, Jean-Daniel
Destarac, Mathias
POLYMER CHEMISTRY, 2014, 5 (03) : 1013 - 1022

← 1 2 3 4 5 →