The microstructure of sintered Sm(Co0.72Fe0.20Cu0.055Zr0.025)7.5 permanent magnet studied by atom probe

被引：192
作者：
Xiong, XY
Ohkubo, T
Koyama, T
Ohashi, K
Tawara, Y
Hono, K
机构：
[1] Natl Inst Mat Sci, Met Nanostruct Grp, Tsukuba, Ibaraki 3050047, Japan
[2] Shin Etsu Chem Co Ltd, Fukui 915, Japan
来源：
ACTA MATERIALIA | 2004年 / 52卷 / 03期
关键词：
SmCo alloys; coercivity; permanent magnets; three-dimensional atom probe; microstructure;
D O I：
10.1016/j.actamat.2003.10.015
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The microstructure and the compositions of the constituent phases in a sintered SM(Co0.72Fe0.20Cu0.055Zr0.025)(7.5) permanent magnet with different cooling processes have been investigated by transmission electron microscopy and the three-dimensional atom probe (3DAP) technique. The Cu concentration in the SmCo5 phase increases during slow cooling from 820 to 520 degreesC, having a wider concentration profile than that of Sm at cell boundaries. Enrichment of Cu at the triple junction of cell boundaries was also found. These results explain the substantial increase in coercivity during the slow cooling process. High resolution transmission electron microscopy and nano-beam electron diffraction analysis have confirmed that the Z-phase is Zr(Co, Fe)(3), having the Be3Nb structure with a approximate to 0.5 nm, c approximate to 2.4 nm. In the Z-phase, Sm is almost completely replaced with Zr during slow cooling. (C) 2003 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：737 / 748
页数：12
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