N-(3-chlorophenyl)benzamide

被引：8

作者：

Gowda, B. Thimme ^{[1
]}

Tokarcik, Miroslav ^{[2
]}

Kozisek, Jozef ^{[2
]}

Sowmya, B. P. ^{[1
]}

Fuess, Hartmut ^{[3
]}

机构：

[1] Mangalore Univ, Dept Chem, Mangalagangothri 574199, Karnataka, India

[2] Slovak Tech Univ, Fac Chem & Food Technol, SK-81237 Bratislava, Slovakia

[3] Tech Univ Darmstadt, Inst Sci Mat, D-64287 Darmstadt, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808001311

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The conformation of the N - H bond in the structure of the title compound (N3CPBA), C13H10ClNO, is anti to the meta chloro substituent in the aniline benzene ring, similar to that observed with respect to the ortho chloro substituent in N-(2-chloro-phen-yl)benzamide (N2CPBA) and meta chloro substituent in N-(3,4-dichloro-phen-yl)benzamide (N34DCPBA), but in contrast to the syn conformation observed with respect to both the ortho and the meta chloro substituents in N-(2,3-dichloro-phen-yl)benzamide (N23DCPBA). The bond parameters in N3CPBA are similar to those in N-phenyl-benzamide, N2CPBA, N23DCPBA, N34DCPBA and other benzanilides. The amide group -NHCO- makes a dihedral angle of 18.2 (2)°with the benzoyl ring, while the dihedral angle between the two benzene rings is 61.0 (1)°. The mol-ecules are linked into chains along the b axis by N - H⋯O hydrogen bonds.

引用

页码：O462 / U2503

页数：9

共 10 条

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