Separation study of cadmium as CdI42- through a bulk liquid membrane containing ketoconazole and oleic acid

被引：18
作者：
Farhadi, K [1 ]
Shamsipur, M
机构：
[1] Urmia Univ, Fac Sci, Dept Chem, Orumiyeh, Iran
[2] Razi Univ, Fac Sci, Dept Chem, Kermanshah, Iran
来源：
ANALYTICAL SCIENCES | 2005年 / 21卷 / 05期
关键词：
D O I：
10.2116/analsci.21.501
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A chloroform membrane system containing a given mixture of ketoconazole and oleic acid was applied for the uphill transport of Cd2+ ions as CdI42-. In an HCl medium the ligand could form a stable ion-pair with CdI42-, which was readily extractable in the membrane phase. A weak basic solution (pH 8) was used as a suitable stripping medium for the quantitative transport of cadmium across the liquid membrane after 120 min. The selectivity and efficiency of Cd2+, transport from an aqueous solution containing other cations, such as Co2+, Cr3+, Ni2+, Fe2+, Mn2+, Pd2+ and Zn2+ ions, were investigated. It was found that none of these cations interfered with Cd2+ transport.
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收藏
页码：501 / 505
页数：5
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