Overcoming Crystallinity Limitations of Aluminium Metal-Organic Frameworks by Oxalic Acid Modulated Synthesis

被引：15
作者：
Canossa, Stefano [1 ,3 ]
Gonzalez-Nelson, Adrian [1 ,2 ]
Shupletsov, Leonid [1 ]
Martin, Maria del Carmen [1 ]
Van der Veen, Monique A. [1 ]
机构：
[1] Delft Univ Technol, Dept Chem Engn, Van der Maasweg 9, NL-2628 BZ Delft, Netherlands
[2] DPI, POB 92, NL-5600 AX Eindhoven, Netherlands
[3] Univ Antwerp, Dept Phys, EMAT, Groenenborgenlaan 171, B-2020 Antwerp, Belgium
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2020年 / 26卷 / 16期
基金：
欧洲研究理事会;
关键词：
aluminium; chelates; crystal growth; metal-organic frameworks; modulated synthesis; SORPTION; MIL-53; ADSORPTION; STRATEGY; OXALATE; MOF;
D O I：
10.1002/chem.201904798
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A modulated synthesis approach based on the chelating properties of oxalic acid (H2C2O4) is presented as a robust and versatile method to achieve highly crystalline Al-based metal-organic frameworks. A comparative study on this method and the already established modulation by hydrofluoric acid was conducted using MIL-53 as test system. The superior performance of oxalic acid modulation in terms of crystallinity and absence of undesired impurities is explained by assessing the coordination modes of the two modulators and the structural features of the product. The validity of our approach was confirmed for a diverse set of Al-MOFs, namely X-MIL-53 (X=OH, CH3O, Br, NO2), CAU-10, MIL-69, and Al(OH)ndc (ndc=1,4-naphtalenedicarboxylate), highlighting the potential benefits of extending the use of this modulator to other coordination materials.
引用
收藏
页码：3564 / 3570
页数：7
相关论文
共 58 条
[1]   Enhanced CO2 Adsorption and Selectivity of CO2/N2 on Amino-MIL-53(Al) Synthesized by Polar Co-solvents [J].
Abid, Hussein Rasool ;
Rada, Zana Hassan ;
Duan, Xiaoguang ;
Sun, Hongqi ;
Wang, Shaobin .
ENERGY & FUELS, 2018, 32 (04) :4502-4510
[2]  
[Anonymous], 2014, ANGEW CHEM INT EDIT
[3]   Changing the Dress to a MOF through Fluorination and Transmetalation. Structural and Gas-Sorption Effects [J].
Balestri, Davide ;
Bassanetti, Irene ;
Canossa, Stefano ;
Gazzurelli, Cristina ;
Bacchi, Alessia ;
Bracco, Silvia ;
Comotti, Angiolina ;
Pelagatti, Paolo .
CRYSTAL GROWTH & DESIGN, 2018, 18 (11) :6824-6832
[4]   New Functionalized Flexible Al-MIL-53-X (X = -Cl, -Br, -CH3, -NO2, -(OH)2) Solids: Syntheses, Characterization, Sorption, and Breathing Behavior [J].
Biswas, Shyam ;
Ahnfeldt, Tim ;
Stock, Norbert .
INORGANIC CHEMISTRY, 2011, 50 (19) :9518-9526
[5]   Anisotropic Water-Mediated Proton Conductivity in Large Iron(II) Metal-Organic Framework Single Crystals for Proton-Exchange Membrane Fuel Cells [J].
Bunzen, Hana ;
Javed, Ali ;
Klawinski, Danielle ;
Lamp, Anton ;
Grzywa, Maciej ;
Kalytta-Mewes, Andreas ;
Tiemann, Michael ;
von Nidda, Hans-Albrecht Krug ;
Wagner, Thorsten ;
Volkmer, Dirk .
ACS APPLIED NANO MATERIALS, 2019, 2 (01) :291-298
[6]  
Cai G., 2017, Angew. Chem, V129, P578
[7]   A Modulator-Induced Defect-Formation Strategy to Hierarchically Porous Metal-Organic Frameworks with High Stability [J].
Cai, Guorui ;
Jiang, Hai-Long .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (02) :563-567
[8]   Giant Negative Area Compressibility Tunable in a Soft Porous Framework Material [J].
Cai, Weizhao ;
Gladysiak, Andrzej ;
Aniola, Michalina ;
Smith, Vincent J. ;
Barbour, Leonard J. ;
Katrusiak, Andrzej .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (29) :9296-9301
[9]   Coordination Modulation Method To Prepare New Metal-Organic Framework-Based CO-Releasing Materials [J].
Carmona, Francisco J. ;
Maldonado, Carmen R. ;
Ikemura, Shuya ;
Romao, Carlos C. ;
Huang, Zhehao ;
Xu, Hongyi ;
Zou, Xiaodong ;
Kitagawa, Susumu ;
Furukawa, Shuhei ;
Barea, Elisa .
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (37) :31158-31167
[10]   The fluoride route: a strategy to crystalline porous materials [J].
Caullet, P ;
Paillaud, JL ;
Simon-Masseron, A ;
Soulard, M ;
Patarin, J .
COMPTES RENDUS CHIMIE, 2005, 8 (3-4) :245-266
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