Texture modeling in carbon-carbon composites based on mesophase precursor matrices

A computational modeling study of texture formation in carbon-carbon composites based on carbon fibers and carbonaceous mesophase precursors is presented. The modeling predictions on texture formation and disclination structures are quantitatively validated with extensive experimental data. The number and type of disclinations displayed by the carbonaceous mesophase matrix is shown to be governed by the elasticity of the mesophase, the carbon fiber mesophase interfacial energy, the size of the fibers, and positional arrangement of the fibers. The simulations provide new insights on the fundamental principles that govern texturing and disclination nucleation, and on how to control the structure of carbon-carbon composites through fiber concentration, fiber cross-section, and fiber-matrix interaction. (c) 2005 Elsevier Ltd. All rights reserved.