Diamination of Domino Aryne Precursor with Sulfonamides

被引：57
作者：
Qiu, Dachuan [1 ]
He, Jia [1 ]
Yue, Xiao [1 ]
Shi, Jiarong [1 ]
Li, Yang [1 ]
机构：
[1] Chongqing Univ, Sch Chem & Chem Engn, 174 Shazheng St, Chongqing 400030, Peoples R China
来源：
ORGANIC LETTERS | 2016年 / 18卷 / 13期
关键词：
THIA-FRIES REARRANGEMENT; FACILE N-ARYLATION; SYNTHETIC APPLICATIONS; ORGANIC-SYNTHESIS; BOND FORMATION; CHEMISTRY; BENZYNE; AMINES; CARBON; AMINOSILANES;
D O I：
10.1021/acs.orglett.6b01334
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of a domino aryne precursor with sulfonamides efficiently afforded both 1,3-diaminobenzenes and trisubstituted 1,3-diaminobenzenes by simply varying the reaction conditions. Mechanistic study supports the sequential formation of two transient aryne intermediates involved in-the reaction.
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收藏
页码：3130 / 3133
页数：4
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