Complexes of N-diisopropoxythiophosphoryl-N′-phenylthiourea with a series of thiophilic metals

被引：0
作者：
Brus'ko, VV [1 ]
Rakhmatullin, AI [1 ]
Zabirov, NG [1 ]
机构：
[1] Kazan State Univ, Kazan, Tatarstan, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2000年 / 70卷 / 10期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Potassium salts of N-diisopropoxythiophosphoryl-N'-phenylthiourea and diisopropoxyphosphoryl-thiobenzamide react with metal salts to form complexes [PhNHC(S)NP(S)(OPr-i)(2)](2)M (M=Cd, Zn, Co, Hg, Ph) and [PhC(S)NP(O)(OPr-i)(2)](2)Cd, whose structure was established by physicochemical methods. The complexes of Cu(II), Ph(IT), and Hg(II) with the first ligand were found to be less stable than with the second. The high (4)J(PH) coupling constants (up to 8.0 Hz) for certain complexes is explained by the favorable configuration of the ligand and the presence of multiple bonds.
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页码：1603 / 1609
页数：7
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