The first PdII complex of a non-heteroatom stabilised carbene ligand

被引:79
作者
Bröring, M [1 ]
Brandt, CD [1 ]
Stellwag, S [1 ]
机构
[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany
关键词
D O I
10.1039/b307160j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Di(p-tolyl)diazomethane reacts with the tripyrrinate Trpy-PdOAcF 1 after activation with NaBArF to yield the first stable Pd-II complex 2 of a non-Arduengo, type carbene ligand, which could be characterised by X-ray crystallography.
引用
收藏
页码:2344 / 2345
页数:2
相关论文
共 19 条
[1]   TRANSITION-METAL-CATALYZED REACTIONS OF DIAZO-COMPOUNDS .1. CYCLOPROPANATION OF DOUBLE-BONDS [J].
ANCIAUX, AJ ;
HUBERT, AJ ;
NOELS, AF ;
PETINIOT, N ;
TEYSSIE, P .
JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (04) :695-702
[2]   Synthesis and molecular structure of four-coordinate neutral and cationic diphenylcarbenerhodium(I) complexes [J].
Bleuel, E ;
Weberndörfer, B ;
Werner, H .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 617 (01) :502-510
[3]   One compound, two structures:: synthesis, structures and reactivity of a novel (tripyrrinato)palladium(II) trifluoracetate complex TrpyPdOAcf [J].
Bröring, M ;
Brandt, CD .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (07) :1391-1395
[4]   Synthetic and structural studies on metal complexes of tripyrrin [J].
Bröring, M ;
Brandt, CD ;
Prikhodovski, S .
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2003, 7 (01) :17-24
[5]   Tripyrrin -: the missing link in the series of oligopyrrolic ligands [J].
Bröring, M ;
Brandt, CD .
CHEMICAL COMMUNICATIONS, 2001, (05) :499-500
[6]   A five coordinate PdII complex stable in solution and in the solid state [J].
Bröring, M ;
Brandt, CD .
CHEMICAL COMMUNICATIONS, 2003, (17) :2156-2157
[7]   Recent advances in asymmetric catalytic metal carbene transformations [J].
Doyle, MP ;
Forbes, DC .
CHEMICAL REVIEWS, 1998, 98 (02) :911-935
[8]   Crystal structures of palladium(II) and copper(II) complexes of meso-phenyl tripyrrinone [J].
Furuta, H ;
Maeda, H ;
Osuka, A .
INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (02) :162-164
[9]   A new general method for the preparation of metal carbene complexes [J].
Gandelman, M ;
Rybtchinski, B ;
Ashkenazi, N ;
Gauvin, RM ;
Milstein, D .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (22) :5372-5373
[10]  
JAUMA A, 1996, MONATSH CHEM, V127, P936