Palladium catalyzed carboxylation of allylstannanes and boranes using CO2

被引：82

作者：

Wu, Jianguo ^{[1
]}

Hazari, Nilay ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 03期

关键词：

CARBON-DIOXIDE; ALLYL STANNANES; METAL-COMPLEXES; CHEMISTRY; INSERTION; ESTERS;

D O I：

10.1039/c0cc03191g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A family of well-defined (eta(3)-allyl)Pd(L)(carboxylate) (L = PR3 or NHC) complexes are by far the most efficient catalysts reported to date for the catalytic carboxylation of allylstannanes into allylcarboxylates using CO2. The substrate scope of this reaction is extended to both substituted allylstannanes and allylboranes.

引用

页码：1069 / 1071

页数：3

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