Three-Component Carbosilylation of Alkenes by Merging Iron and Visible-Light Photocatalysis

被引：51
|
作者：
Neogi, Sukanya [1 ]
Ghosh, Asim Kumar [1 ]
Mandal, Saurodeep [1 ]
Ghosh, Debashis [2 ]
Ghosh, Sumit [1 ]
Hajra, Alakananda [1 ]
机构：
[1] Visva Bharati, Dept Chem, Santini Ketan 731235, W Bengal, India
[2] St Josephs Coll Autonomous, Dept Chem, Bangalore 560027, Karnataka, India
来源：
ORGANIC LETTERS | 2021年 / 23卷 / 16期
关键词：
PHOTOREDOX; ALKYNES;
D O I：
10.1021/acs.orglett.1c02322
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A mild, efficient, and one-pot protocol for three-component carbosilylation of alkenes with imidazoheterocycle and silanes has been developed by merging iron(II) and visible-light photocatalysis. This C-C and C-Si bond-forming method provides functionalized organosilicon derivatives having imidazoheterocycles moieties in good yields. The reaction possibly proceeds through a radical pathway.
引用
收藏
页码：6510 / 6514
页数：5
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