Catalytic conversion of butadiene to ethylbenzene over the nanoporous nickel(II) phosphate, VSB-1

被引：57
作者：
Chang, JS
Park, SE
Gao, QM
Férey, G
Cheetham, AK
机构：
[1] Korea Res Inst Chem Technol, Catalysis Ctr Mol Engn, Taejon 305606, South Korea
[2] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
[3] Univ Versailles St Quentin, CNRS, Inst Lavoisier, UMR 173, F-78035 Versailles, France
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 09期
关键词：
D O I：
10.1039/b009160j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The large-pore nickel(ii) phosphate, VSB-1, shows excellent selectivity (> 80%) for the dehydrocyclodimerization of butadiene to ethylbenzene at 400 degreesC; conversion to 4-vinylcyclohexene and oligomeric byproducts is <5% in each case.
引用
收藏
页码：859 / 860
页数：2
相关论文
共 23 条
[1]  
Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO
[2]  
2-U
[3]  
CHEN JS, 1994, ANGEW CHEM INT EDIT, V33, P639, DOI 10.1002/anie.199406391
[4]   Oxidative dehydrogenation of 4-vinylcyclohexene into styrene over ZrO2 catalyst promoted with Fe2O3 and CaO [J].
Choi, YS ;
Park, YK ;
Chang, JS ;
Park, SE ;
Cheetham, AK .
CATALYSIS LETTERS, 2000, 69 (1-2) :93-101
[5]  
CORBIN DR, 1986, INORG CHEM, V25, P2280
[6]   The quest for extra-large pore, crystalline molecular sieves [J].
Davis, ME .
CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (11) :1745-1750
[7]   CATALYSIS OF DIELS-ALDER REACTIONS BY ZEOLITES [J].
DESSAU, RM .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (15) :1167-1168
[8]   Effect of thermal treatment on various characteristics of nickel/aluminum phosphate catalysts [J].
El-Hakam, SA ;
El-Khouly, AA ;
Khder, AS .
APPLIED CATALYSIS A-GENERAL, 1999, 185 (02) :247-257
[9]   Syntheses and characterizations of chiral tetrahedral cobalt phosphates with zeolite ABW and related frameworks [J].
Feng, PY ;
Bu, XH ;
Tolbert, SH ;
Stucky, GD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (10) :2497-2504
[10]   Porous materials -: Prospects for giant pores [J].
Férey, G ;
Cheetham, AK .
SCIENCE, 1999, 283 (5405) :1125-1126
123