Electrochemical reduction of CCl2F2 on nafion solid polymer electrolyte composite electrodes

被引：16

作者：

Delli, E ^{[1
]}

Kouloumtzoglou, S ^{[1
]}

Kyriacou, G ^{[1
]}

Lambrou, C ^{[1
]}

机构：

[1] Aristotelian Univ Salonika, Dept Chem Engn, GR-54006 Thessloniki, Greece

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 16期

关键词：

D O I：

10.1039/a804210a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemical reduction of CCl2F2 (CFC-12) was carried out at Pd, An, Cu and Ag cathodes, which were chemically deposited on Nafion 117 (H+ form) membrane; the main electrolysis product at -1.0 V vs. Ag/AgCl at Au, Pd and Cu was CH4, with current efficiencies (CE) of 14, 15 and 47% respectively, while at Ag cathode, in addition to CH4, a considerable quantity of CH2F2 (CE 60%) was also detected, which might be used as a new technology refrigerant.

引用

页码：1693 / 1694

页数：2

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