Study of copper forms of the synthetic zeolite ZSM5 containing ethylenediamine

被引：6
|
作者：
Reháková, M
Wadsten, T
Nagyová, S
Bastl, Z
Briancin, J
机构：
[1] Safarik Univ, Fac Sci, Kosice 04154, Slovakia
[2] Dev & Res Wadsten AB, S-11327 Stockholm, Sweden
[3] Tech Univ, Dept Phys, Kosice 04200, Slovakia
[4] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, CR-18223 Prague, Czech Republic
[5] SAV, Inst Mat Res, Kosice 04353, Slovakia
来源：
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2001年 / 39卷 / 1-2期
关键词：
synthetic zeolite; ZSM5; ethylenediamine; copper; complex; NMR; XPS; DTA;
D O I：
10.1023/A:1008107029260
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Synthetic zeolite ZSM5 and its copper forms containing ethylenediamine (en) have been investigated by X-ray powder diffractometry, NMR and X-ray photoelectron spectroscopies, CHN, EDS and thermal analyses. Copper cations exchanged into the channels of synthetic zeolite ZSM5 formed coordination complexes with ethylenediamene. By different modes of preparation we obtained three Cu-en-ZSM5 zeolitic products with different composition, colour and other properties. The content of the ethylenediamine in the zeolitic products was 1.5-6 wt.% (dependent of the mode of preparation).
引用
收藏
页码：181 / 186
页数：6
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