Novel high-Q x f (1-x)CeO2-xCaF2 (0.2 ≤ x ≤ 0.6) microwave dielectric ceramics sintered at medium temperatures

被引:2
作者
Gao, Yufeng [1 ]
Jiang, Juan [1 ]
Wang, Jinzhao [1 ]
Gan, Lin [1 ]
Zhang, Tianjin [1 ]
机构
[1] Hubei Univ, Sch Mat Sci & Engn, Collaborat Innovat Ctr Adv Organ Chem Mat Coconst, Minist Educ,Key Lab Green Preparat & Applicat Fun, 368 Youyi Ave, Wuhan 430062, Hubei, Peoples R China
基金
中国国家自然科学基金;
关键词
Microwave dielectric ceramics; Cubic fluorite structure; CeO2; PHASE; OXIDE; CERIA;
D O I
10.1007/s43207-022-00223-y
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this work, a new binary microwave dielectric ceramic system of (1 - x)CeO2-xCaF(2) (0.2 <= x <= 0.6) was fabricated at medium sintering temperatures. The compositional effects of on the sintering behavior, phase compositions, microstructures, and microwave dielectric properties of the samples were studied. High relative density levels (> 95%) were achieved in the (1 - x)CeO2-xCaF(2) samples at the sintering temperatures ranging from 1100 to 1350 degrees C. An increase in the content of CaF2 resulted in a decrease in the dielectric constant, an increase in the Q x f level, and a negative shift of the tau(f) value. The optimal microwave dielectric properties of epsilon(r) = 11.3, Q x f = 53,000 GHz, and tau(f) = - 102 ppm/degrees C were obtained in the sample of (1 - x)CeO2-xCaF(2) with x = 0.6 when sintered at 1300 degrees C.
引用
收藏
页码:929 / 935
页数:7
相关论文
共 18 条
[1]   A new high-Qxf Li4NbO4F microwave dielectric ceramic for LTCC applications [J].
Chu, Xin ;
Jiang, Juan ;
Wang, Jinzhao ;
Wu, Yuanchuang ;
Gan, Lin ;
Zhang, Tianjin .
CERAMICS INTERNATIONAL, 2021, 47 (03) :4344-4351
[2]  
Hakki B.W., 1960, IEEE T MICROW THEORY, V8, P402, DOI DOI 10.1109/TMTT.1960.1124749
[3]   Effect of grain size and secondary phase on microwave dielectric properties of Ba(Mg1/3Ta2/3)O3 and Ba([Mg,Zn]1/3Ta2/3)O3 systems [J].
Ichinose, N ;
Shimada, T .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2006, 26 (10-11) :1755-1759
[4]   A brief review on ceria based solid electrolytes for solid oxide fuel cells [J].
Jaiswal, Nandini ;
Tanwar, Khagesh ;
Suman, Rathod ;
Kumar, Devendra ;
Upadhyay, Shail ;
Parkash, Om .
JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 781 :984-1005
[5]   The microwave dielectric properties of xTiO2(1-x)CeO2 ceramics [J].
Kim, DH ;
Lim, SK ;
An, C .
MATERIALS LETTERS, 2002, 52 (03) :240-243
[6]   Effect of doping on the dielectric properties of cerium oxide in the microwave and far-infrared frequency range [J].
Santha, NL ;
Sebastian, MT ;
Mohanan, P ;
Alford, NM ;
Sarma, K ;
Pullar, RC ;
Kamba, S ;
Pashkin, A ;
Samukhina, P ;
Petzelt, J .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2004, 87 (07) :1233-1237
[7]   Low-fired fluoride microwave dielectric ceramics with low dielectric loss [J].
Song, Xiao-Qiang ;
Du, Kang ;
Li, Jie ;
Lan, Xue-Kai ;
Lu, Wen-Zhong ;
Wang, Xiao-Hong ;
Lei, Wen .
CERAMICS INTERNATIONAL, 2019, 45 (01) :279-286
[8]   High-Qxf CaWO4 ceramics sintered at low temperatures with the addition of Li2CeO3 [J].
Tang, Yu ;
Hu, Xueqi ;
Jiang, Juan ;
Wang, Jinzhao ;
Gan, Lin ;
Zhang, Tianjin .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2021, 32 (04) :4749-4754
[9]   Catalytic properties of ceria and CeO2-containing materials [J].
Trovarelli, A .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1996, 38 (04) :439-520
[10]   Dielectric and ferroelectric behavior of an incipient ferroelectric Sr(1-3x/2)CexTiO3 novel solid solution [J].
Ullah, Burhan ;
Lei, Wen ;
Wang, Xiao-Hong ;
Fan, Gui-Fen ;
Wang, Xiao-Chuan ;
Lu, Wen-Zhong .
RSC ADVANCES, 2016, 6 (94) :91679-91688