Nickel-catalysed synthesis of 3-chloroanilines and chloro aminopyridines via cross-coupling reactions of aryl and heteroaryl dichlorides with amines

被引：49

作者：

Desmarets, C ^{[1
]}

Schneider, R ^{[1
]}

Fort, Y ^{[1
]}

机构：

[1] Univ Nancy 1, UMR 7565, F-54506 Vandoeuvre Les Nancy, France

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 02期

关键词：

catalysis; nickel; amination; chloroanilines; chloro aminopyridines;

D O I：

10.1016/S0040-4039(00)01931-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selective monoamination of aryl and heteroaryl dichlorides has been carried out using a catalyst combination of Ni(0) associated to 2,2'-bipyridine. The synthesis of novel 3-chloroanilines and chloro aminopyridines in good to excellent yields is allowed using an excess of amine, 10 or 20 mol% catalyst and short reaction times. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：247 / 250

页数：4

共 35 条

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