Catalytic hydrochlorination of unactivated olefins with para-toluenesulfonyl chloride

被引：155
作者：
Gaspar, Boris [1 ]
Carreira, Erick M. [1 ]
机构：
[1] ETH Honggerberg, Organ Chem Lab, CH-8093 Zurich, Switzerland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 31期
关键词：
alkenes; cobalt; homogeneous catalysis; hydrochlorination; silanes;
D O I：
10.1002/anie.200801760
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Asimple solution to a long-standing problem: The hydrochlorination of unactivated alkenes, which is shown in the Scheme, is catalyzed by simple cobalt complexes and proceeds under very mild conditions. The ready availability of all components and the ease of execution render the method very convenient. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码：5758 / 5760
页数：3
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