Metal organic frameworks

被引:0
|
作者
Sonker, Muskan [1 ]
Tiwary, Saurabh Kr [2 ]
Shreyash, Nehil [2 ]
Bajpai, Sushant [3 ]
Ray, Mainak [4 ]
Kar, Sanjay Kumar [5 ]
Balathanigaimani, M. S. [6 ]
机构
[1] Georgia Inst Technol, Dept Chem & Biomol Engn, Atlanta, GA 30318 USA
[2] Univ Houston, Dept Chem & Biomol Engn, Houston, TX USA
[3] Univ Oklahoma, Dept Chem Biol & Mat Engn, Norman, OK USA
[4] HPCL Mittal Energy Ltd Bathinda, R&D & Innovat, Bhatinda, Punjab, India
[5] Rajiv Gandhi Inst Petr Technol, Dept Management Sci, Jais, India
[6] Rajiv Gandhi Inst Petr Technol, Dept Chem Engn & Biochem Engn, Jais, India
关键词
Metal organic frameworks; Ammonia; Fuel cell; Alternative fuel; Ammonia economy; AMMONIA FUEL-CELL; COX-FREE HYDROGEN; PERFORMANCE-CHARACTERISTICS; COORDINATION POLYMERS; WATER ELECTROLYSIS; OXIDE COMPOSITES; DIRECT-INJECTION; DIESEL-ENGINE; ELECTRIC CARS; STORAGE;
D O I
10.1016/j.jclepro.2022.133960
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This article is a roadmap for researchers in this field to look for an efficient and reliable alternative for fossil fuels in the form of ammonia. We have discussed different storage techniques, with one of them being 'solid ammonia storage method' using MOFs and metal ammine complexes as a better option to deal with ammonia toxicity. Besides, we have discussed various approaches of direct and indirect ammonia being used in internal combustion engines as fuel or within fuel cells for creating a sustainable energy source for the onboard vehicular application. To discuss ammonia's feasibility as a commercial fuel, a detailed discussion on ammonia economy is important. So, in the later sections of the article, we have discussed ammonia economy, emerging technologies for ammonia production, cost analysis, investment, the economics of vehicle engines and fuel cells, and opportunities ahead. In the article, apart from just advocating the feasibility of using ammonia as a future fuel, the authors have also talked about its downsides, associated challenges, and how there are alternative pathways to use ammonia indirectly as well. The authors believe that in the literature, very few articles present such a broad discussion on ammonia's feasibility as a future fuel. Thus, we believe this article will help the readers in formulating their own opinion regarding ammonia and work on finding the right fuel for a sustainable future.
引用
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页数:27
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