Perfluoro-4-methyl-1,3-dioxole:: a new monomer for high-Tg amorphous fluoropolymers

被引：19

作者：

Russo, A ^{[1
]}

Navarrini, W ^{[1
]}

机构：

[1] Solvay Solexis, R&D Ctr, I-20021 Bollate, MI, Italy

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2004年 / 125卷 / 01期

关键词：

bis(fluoroxy)difluoromethane; reactivity; synthesis; chlorofluoro propenes; isomerization; dioxolanes; perfluorodioxoles;

D O I：

10.1016/j.jfluchem.2003.10.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 4-Chloro-5-trifluoromethyl-2,2,4-trifluoro-1,3-dioxolane (1) was synthesised by reaction of CF2(OF)(2) with CF3-CH=CFCl; the elimination of HCl from (1) in basic conditions led to the formation of dioxole perfluoro-4-methyl-1,3-dioxole (2). Both these synthetic steps gave the corresponding product in high yield. A new synthetic route for the preparation of CF3-CH=CFCl, starting from CF2ClBr and CH2=CF2, together with some examples of polymerisation products obtained by reaction of dioxole (2) with fluoroolefins are also reported. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：73 / 78

页数：6

共 10 条

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Sokolov, V. I.
Goriachuk, I. O.
Zavarzin, I. V.
Molchanova, S. I.
Pogodina, Yu. E.
Polunin, E. V.
Yarosch, A. A.
RUSSIAN CHEMICAL BULLETIN, 2019, 68 (03) : 559 - 564
[2] New copolymers of perfluoro-2-ethyl-2-methyl-1,3-dioxole and perfluorovinyl ether with low non-monotonic refractive index
V. I. Sokolov
I. O. Goriachuk
I. V. Zavarzin
S. I. Molchanova
Yu. E. Pogodina
E. V. Polunin
A. A. Yarosch
Russian Chemical Bulletin, 2019, 68 : 559 - 564
[3] FLUORINATED DIOXOLANES .3. NUCLEOPHILIC REACTIONS OF PERFLUORO-4-METHYL-1,3-DIOXOLANES
YUMINOV, VS
KARTSOV, SV
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BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1989, 38 (04): : 845 - 849
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Harders, Abby N.
Sturd, Erin R.
Wallisch, Luke
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Mendoza-Apodaca, Yuniva
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INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2023, 62 (09) : 4054 - 4063
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[6] Molecular characterization of a amorphous perfluoropolymer: Poly (perfluoro-2-methylene-4-methyl-1,3-dioxolane).
Mikes, F
Teraoka, L
Koike, Y
Okamoto, Y
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U646 - U646
[7] Synthesis and characterization of an amorphous perfluoropolymer: Poly(perfluoro-2-methylene-4-methyl-1,3-dioxolane)
Mikes, F
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MACROMOLECULES, 2005, 38 (10) : 4237 - 4245
[8] Positron annihilation lifetime and Doppler broadening studies of amorphous fluoropolymer-poly (2,2-bis trifluoro 4,5 difluoro 1,3-dioxole
Davies, William J.
Pethrick, Richard A.
1600, Pergamon Press Ltd, Oxford, United Kingdom (30):
[9] A NEW CONVENIENT SYNTHESIS OF TRISUBSTITUTED 1,3-DIOXOLE-4-CARBOXYLATES FROM METHYL 2-DIAZO-3-OXOBUTYRATE AND ALDEHYDES
ALONSO, ME
CHITTY, AW
TETRAHEDRON LETTERS, 1981, 22 (42) : 4181 - 4184
[10] POLYISOBUTYLENE-CONTAINING BLOCK POLYMERS BY SEQUENTIAL MONOMER ADDITION .4. NEW TRIBLOCK THERMOPLASTIC ELASTOMERS COMPRISING HIGH TG STYRENIC GLASSY SEGMENTS - SYNTHESIS, CHARACTERIZATION AND PHYSICAL-PROPERTIES
PUSKAS, JE
KASZAS, G
KENNEDY, JP
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