Inclusion Complex of β-cyclodextrin with CTAB in Aqueous Solution

被引：4
|
作者：
Chen, Xiao-ming [1 ,2 ]
机构：
[1] Anhui Univ Architecture, Sch Mat & Chem Engn, Hefei 230601, Peoples R China
[2] Anhui Key Lab Adv Bldg Mat, Hefei 230601, Peoples R China
来源：
CHINESE JOURNAL OF CHEMICAL PHYSICS | 2011年 / 24卷 / 04期
关键词：
Cetyltrimethylammonium bromide; KBr; beta-cyclodextrin; Viscosity; SURFACTANT INCLUSION; ANIONIC SURFACTANTS; BINDING CONSTANTS; ASSOCIATION; NMR; MICELLES; ALCOHOLS;
D O I：
10.1088/1674-0068/24/04/484-488
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Cetyltrimethylammonium bromide (CTAB)/potassium bromide (KBr) micellar system has been used as a viscosity probe to study the inclusion complexation between beta-cyclodextrin (beta-CD) and CTAB. Viscosity measurements show that the inclusion complexation between beta-CD and CTAB may cause the breakdown of CTAB/KBr wormlike micelles, resulting in the decrease of the solution viscosity. The viscosity minimum at C(beta-CD)/C(CTAB)=2 indicate the molecular ratio of host molecule to guest molecule is 2:1 in the beta-CD/CTAB inclusion complex.
引用
收藏
页码：484 / 488
页数：5
相关论文
共 50 条
  • [31] Inclusion complexes of Sulconazole with β-cyclodextrin and hydroxypropyl β-cyclodextrin: characterization in aqueous solution and in solid state
    Mariana Spulber
    Mariana Pinteala
    Valeria Harbagiu
    Bogdan C. Simionescu
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2008, 61 : 41 - 51
  • [32] Fluorescence enhancement of 1-napthol-5-sulfonate by forming inclusion complex with β-cyclodextrin in aqueous solution
    Abdel-Shafi, Ayman A.
    Al-Shihry, Shar S.
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2009, 72 (03) : 533 - 537
  • [33] Spectrofluorimetric study of the inclusion complex of 7-hydroxymethylnalidixic acid with gamma-cyclodextrin in aqueous solution
    DuranMeras, I
    DelaPena, AM
    Salinas, F
    Caceres, IR
    APPLIED SPECTROSCOPY, 1997, 51 (05) : 684 - 688
  • [34] Inclusion complexes of Sulconazole with β-cyclodextrin and hydroxypropyl β-cyclodextrin:: characterization in aqueous solution and in solid state
    Spulber, Mariana
    Pinteala, Mariana
    Harbagiu, Valeria
    Simionescu, Bogdan C.
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2008, 61 (1-2) : 41 - 51
  • [35] Voltammetric behavior of the C60-γ-cyclodextrin inclusion complex (1:2) on hmde in an aqueous solution
    Li, Mei-Xian
    Li, Nan-Qiang
    Gu, Zhen-Nan
    Zhou, Xi-Huang
    Sun, Yi-Liang
    Wu, Yong-Qing
    Electrochimica Acta, 41 (18): : 2897 - 2901
  • [36] Spectroscopic and electrochemical studies on the interaction of an inclusion complex of β-cyclodextrin/fullerene with bovine serum albumin in aqueous solution
    Zhang, Mei-Fang
    Fu, Li
    Wang, Jia
    Xu, Zi-Qiang
    Jiang, Feng-Lei
    Liu, Yi
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2012, 228 (01) : 28 - 37
  • [37] Insulation effect of an inclusion complex formed by polyaniline and β-cyclodextrin in solution
    Shimomura, T
    Yoshida, K
    Ito, K
    Hayakawa, R
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2000, 11 (8-12) : 837 - 839
  • [38] NMR spectroscopic study of the inclusion complex of desloratadine with β-cyclodextrin in solution
    Syed Mashhood Ali
    Santosh Kumar Upadhyay
    Arti Maheshwari
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2007, 59 : 351 - 355
  • [39] NMR spectroscopic study of the inclusion complex of desloratadine with β-cyclodextrin in solution
    Ali, Syed Mashhood
    Upadhyay, Santosh Kumar
    Maheshwari, Arti
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2007, 59 (3-4) : 351 - 355
  • [40] Ternary inclusion complexes of γ-cyclodextrin with resorufin and organic cations in aqueous solution
    Hamai, Sanyo
    Bulletin of the Chemical Society of Japan, 2007, 80 (08): : 1527 - 1533
12345