Sc(BINOL)2Li:: a new heterobimetallic catalyst for the asymmetric Strecker reaction

被引：96

作者：

Chavarot, M ^{[1
]}

Byrne, JJ ^{[1
]}

Chavant, PY ^{[1
]}

Vallée, Y ^{[1
]}

机构：

[1] Univ Grenoble 1, CNRS, UMR, LEDSS, F-38041 Grenoble, France

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 08期

关键词：

D O I：

10.1016/S0957-4166(01)00144-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new chiral heterobimetallic complex Sc(BINOL)(2)Li 1 was prepared and used as a catalyst in the enantioselective addition of a cyanide source (HCN or TMSCN) to several imines. High conversion rates and enantiomeric e excesses (e.e.s) as high as 95% were obtained. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1147 / 1150

页数：4

共 25 条

[1] Asymmetric Strecker reactions of ketimines catalysed by titanium-based complexes
Byrne, JJ
Chavarot, M
Chavant, PY
Vallée, Y
[J]. TETRAHEDRON LETTERS, 2000, 41 (06) : 873 - 876
[2] BYRNE JJ, 2000, Patent No. 0075104
[3] ENANTIOSPECIFIC SYNTHESIS OF A RIGID, C-2 SYMMETRIC, CHIRAL GUANIDINE BY A NEW AND DIRECT METHOD
COREY, EJ
OHTANI, M
[J]. TETRAHEDRON LETTERS, 1989, 30 (39) : 5227 - 5230
[4] Enantioselective synthesis of α-amino nitriles from N-benzhydryl imines and HCN with a chiral bicyclic guanidine as catalyst
Corey, EJ
Grogan, MJ
[J]. ORGANIC LETTERS, 1999, 1 (01) : 157 - 160
[5] Iida T, 1998, ANGEW CHEM INT EDIT, V37, P2223, DOI 10.1002/(SICI)1521-3773(19980904)37:16<2223::AID-ANIE2223>3.0.CO
[6] 2-Z
[7] Catalytic asymmetric Strecker synthesis.: Preparation of enantiomerically pure α-amino acid derivatives from aldimines and tributyltin cyanide or achiral aldehydes, amines, and hydrogen cyanide using a chiral zirconium catalyst
Ishitani, H
Komiyama, S
Hasegawa, Y
Kobayashi, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (05) : 762 - 766
[8] RETRACTED: Asymmetric catalysis of the Strecker amino acid synthesis by a cyclic dipeptide (Retracted article. See JUN, 2023)
Iyer, MS
Gigstad, KM
Namdev, ND
Lipton, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (20) : 4910 - 4911
[9] MOLECULAR-ORBITAL AND EXPERIMENTAL STUDIES ON THE PHOTOINDUCED DECARBOXYLATION OF PYRETHROID MODEL ESTERS
KATAGI, T
MIKAMI, N
MATSUDA, T
MIYAMOTO, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1989, (07): : 779 - 782
[10] Kobayashi S, 2000, CHIRALITY, V12, P540, DOI 10.1002/(SICI)1520-636X(2000)12:5/6<540::AID-CHIR42>3.0.CO

← 1 2 3 →