Structure and magnetic properties of bulk nanocrystalline SmCo7-xHfx sintered magnets

被引:12
作者
Zhang, Dongtao [1 ]
Yue, Ming [1 ]
Pan, Lijun [1 ]
Li, Yangchao [1 ]
Xu, Gang [1 ]
Liu, Weiqiang [1 ]
Zhang, Jiuxing [1 ]
Liu, Xubo [2 ,3 ]
Altounian, Zaven [2 ,3 ]
机构
[1] Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100022, Peoples R China
[2] McGill Univ, Dept Phys, Montreal, PQ H3A 2T8, Canada
[3] McGill Univ, Ctr Phys Mat, Montreal, PQ H3A 2T8, Canada
关键词
D O I
10.1063/1.2830557
中图分类号
O59 [应用物理学];
学科分类号
摘要
The structure and magnetic properties of the bulk nanocrystalline SmCo7-xHfx (x=0,0.1,0.2) magnets prepared using the spark plasma sintering technology were studied. SmCo7-xHfx magnet exhibits a single phase with the TbCu7-type structure. The Rietveld structure refinement results show that Hf prefers to occupy the 1a site, which in turn leads to an enhancement of the anisotropy field of the SmCo7 compounds. Microstructure analysis indicates that the average grains size is about 35 nm. With increasing Hf contents from x=0 to 0.2, the coercivity increases from 0.89 to 2.08 T. The coercivity of SmCo6.8Hf0.2 magnet decreases almost linearly from 2.08 to 0.4 T with increasing temperatures from 300 to 773 K. (C) 2008 American Institute of Physics.
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页数:3
相关论文
共 14 条
[1]   Magnetic behavior of Sm-Co-based permanent magnets during order/disorder phase transformations [J].
Aich, S ;
Kostogorova, J ;
Shield, JE .
JOURNAL OF APPLIED PHYSICS, 2005, 97 (10)
[2]   Magnetic and structural properties of SmCo7-xCux alloys [J].
Al-Omari, IA ;
Yeshurun, Y ;
Zhou, J ;
Sellmyer, DJ .
JOURNAL OF APPLIED PHYSICS, 2000, 87 (09) :6710-6712
[3]   Phase equilibria at 1150 degrees C in the Co-rich alloys Sm-Co-Zr and structure of the 1:7 phase [J].
Derkaoui, S ;
Valignat, N ;
Allibert, CH .
JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 232 (1-2) :296-301
[4]   Magnetism and phase stability of R(Co,M)7 pseudobinary intermetallics with TbCu7-type structure [J].
Guo, Yongquan ;
Feng, Weicun ;
Li, Wei ;
Luo, Jun ;
Liang, Jingkui .
JOURNAL OF APPLIED PHYSICS, 2007, 101 (02)
[5]   Structural stability and magnetic properties of SmCo7-xGax -: art. no. 192513 [J].
Guo, YQ ;
Li, W ;
Feng, WC ;
Luo, J ;
Liang, JK ;
He, QJ ;
Yu, XJ .
APPLIED PHYSICS LETTERS, 2005, 86 (19) :1-3
[6]   ANOMALOUS MAGNETIC-BEHAVIOR OF CE1-XRXCOS, CE1-XHFXCO5 ALLOYS [J].
GUPTA, HO ;
MALIK, SK ;
WALLACE, WE .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1984, 42 (03) :239-242
[7]   Structure and magnetic properties of SmCo7-xZrx alloys (x=0-0.8) [J].
Huang, MQ ;
Wallace, WE ;
McHenry, M ;
Chen, Q ;
Ma, BM .
JOURNAL OF APPLIED PHYSICS, 1998, 83 (11) :6718-6720
[8]   Magnetic and structural properties of SmCo7-xTix magnets [J].
Jiang, CB ;
Venkatesan, M ;
Gallagher, K ;
Coey, JMD .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2001, 236 (1-2) :49-55
[9]   Effect of lattice relaxation on magnetic anisotropy:: Zr-doped Sm2Co17 -: art. no. 012404 [J].
Larson, P ;
Mazin, II .
PHYSICAL REVIEW B, 2004, 69 (01)
[10]   Calculation of magnetic anisotropy energy in SmCo5 -: art. no. 214405 [J].
Larson, P ;
Mazin, II ;
Papaconstantopoulos, DA .
PHYSICAL REVIEW B, 2003, 67 (21)