Biobased synthesis of acrylonitrile from glutamic acid

被引：60
|
作者：
Le Notre, Jerome [1 ]
Scott, Elinor L. [1 ]
Franssen, Maurice C. R. [2 ]
Sanders, Johan P. M. [1 ]
机构：
[1] Univ Wageningen & Res Ctr, NL-6700 AA Wageningen, Netherlands
[2] Univ Wageningen & Res Ctr, Organ Chem Lab, NL-6703 HB Wageningen, Netherlands
来源：
GREEN CHEMISTRY | 2011年 / 13卷 / 04期
关键词：
ALPHA-AMINO-ACIDS; DISTILLERS DRIED GRAINS; HYDROGEN-PEROXIDE; CARBOXYLIC-ACIDS; OXIDATIVE DECARBOXYLATION; ELIMINATION-REACTION; NITRILES; CONVERSION; BROMINATION; BROMOPEROXIDASE;
D O I：
10.1039/c0gc00805b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Glutamic acid was transformed into acrylonitrile in a two step procedure involving an oxidative decarboxylation in water to 3-cyanopropanoic acid followed by a decarbonylation-elimination reaction using a palladium catalyst.
引用
收藏
页码：807 / 809
页数：3
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