47,49Ti NMR:: hyperfine interactions in oxides and metals

被引：33
作者：
Bastow, TJ [1 ]
Gibson, MA [1 ]
Forwood, CT [1 ]
机构：
[1] CSIRO, Div Mfg Sci & Technol, Clayton, Vic 3139, Australia
来源：
SOLID STATE NUCLEAR MAGNETIC RESONANCE | 1998年 / 12卷 / 04期
关键词：
Ti-47; Ti-49; NMR; hyperfine interactions; oxides; metals; intermetallics;
D O I：
10.1016/S0926-2040(98)00066-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A Ti-47,Ti-49 NMR characterisation is given of various polymorphs of TiO2 (anatase, rutile and brookite), Ti2O3, perovskites CaTiO3 and BaTiO3, FeTiO3, TiB2, titanium metal, the titanium aluminides Ti3Al, TiAl, TiAl2, TiAl3, and TiAg. Values of chemical or Knight shift, nuclear quadrupole coupling constant and asymmetry parameter were derived from the (1/2, - 1/2) powder lineshapes, For TiB2, titanium metal, TiAl, and TiAl3, where +/-(1/2, 3/2), and higher satellite transitions were observed, a value for the axial component of the Knight shift was obtained. (C) 1998 Elsevier Science B.V. All rights reserved.
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页码：201 / 209
页数：9
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