Effect of water vapor generation on cell polarization in active area of anode-supported solid oxide fuel cells

被引:3
作者
Kim, Jungmyung [1 ]
Ali, Ehtesham [1 ]
Kim, Minwoo [2 ]
Lim, Hyungtae [3 ]
Park, Heesung [4 ]
机构
[1] Changwon Natl Univ, Grad Sch Mech Engn, Chang Won 51140, South Korea
[2] Changwon Natl Univ, Grad Sch Mat Sci & Engn, Chang Won 51140, South Korea
[3] Changwon Natl Univ, Dept Mat Sci & Engn, Chang Won 51140, South Korea
[4] Changwon Natl Univ, Dept Mech Engn, Chang Won 51140, South Korea
关键词
Solid oxide fuel cell; Anode supported; Coin cell; Rectangular channel; TRANSPORT PHENOMENA; ELECTROCHEMICAL PERFORMANCE; INTERMEDIATE TEMPERATURE; CONVERSION IMPEDANCE; SOFC; MODEL;
D O I
10.1007/s00231-019-02732-9
中图分类号
O414.1 [热力学];
学科分类号
摘要
In this paper, a three-dimensional computational fluid dynamics model based on the finite volume method is developed for an anode-supported solid oxide fuel cell with an active area of 1.54 cm(2). The numerical model including electrochemical reaction has been compared with experimental data obtained under the same conditions to verify the reliability of the code, air and fuel concentrations at the anode and cathode of the cell were shown and analyzed according to the three fuel utilization rates. The calculated current density of the SOFC has been affected by the flow velocity and gas concentration due to water vapor generation. The electrochemical reaction generates water vapors at the reaction sides which impedes gas diffusion. We have shown the streamlines of gas flow distracted by increased water vapor concentration. Consequently, the operating conditions of SOFC should be determined by considering the effects of water vapor generation for the practical applications. We have verified the water vapor generation in SOFC which significantly affects the performance.
引用
收藏
页码:617 / 625
页数:9
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