Enhanced Catalytic Performances for Guaiacol Aqueous Phase Hydrogenation over Ruthenium Supported on Mesoporous TiO2 Hollow Spheres Embedded with SiO2 Nanoparticles

被引：17

作者：

Han, Bingbing ^{[1
]}

Bao, Zhikang ^{[1
]}

Liu, Tianzhu ^{[1
]}

Zhou, Hu ^{[1
]}

Zhuang, Guilin ^{[1
]}

Zhong, Xing ^{[1
]}

Deng, Shengwei ^{[1
]}

Wang, Jianguo ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn, Inst Ind Catalysis, Hangzhou 310032, Zhejiang, Peoples R China

来源：

CHEMISTRYSELECT | 2017年 / 2卷 / 29期

基金：

中国国家自然科学基金;

关键词：

ruthenium; mesoporous TiO2; aqueous phase; hydrogenation; guaiacol; LIQUID-PHASE; SELECTIVE HYDROGENATION; PHENOLIC-COMPOUNDS; RU NANOPARTICLES; ACTIVATED CARBON; HYDRODEOXYGENATION; LIGNIN; EFFICIENT; CONVERSION; CYCLOHEXANONE;

D O I：

10.1002/slct.201702013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic hydrogenation of lignin-derived phenolic compounds with high catalytic activity and yield is important for the efficient utilization of lignin derivatives. In this study, a series of mesoporous TiO2 sphere-supported Ru catalysts were prepared, characterized, and used for hydrogenating guaiacol in aqueous solutions. Both the 100% conversion and 84.2% cyclohexanol yield were achieved using Ru supported on mesoporous TiO2 hollow spheres embedded with SiO2 nanoparticles (Ru-TiO2-eSiO(2)) catalyst under 1.5 MPa H-2 at 160 degrees C for 100 min. Catalyst characterization indicated that the outstanding catalytic performance of the Ru-TiO2-eSiO(2) is mainly due to its unique spherical structure and acidic properties. The TiO2 shell is polyporous with numerous 3.8 nm mesopores that favor mass transfer efficiency in the reaction process. Moreover, the moderate acidic sites of the catalyst promoted the removal of the -OCH3 group from guaiacol and improve cyclohexanol yield. The catalyst exhibited good water resistance and its catalytic activity presented no obvious loss after recycling for 5 times.

引用

页码：9599 / 9606

页数：8

共 51 条

[1] One step thermal conversion of lignin to the gasoline range liquid products by using zeolites as additives [J].