Magnetic ZnO@CuO@Iron ore nanocomposites as a green and highly efficient heterogeneous nanocatalyst for solventless synthesis of α-aminophosphonates

被引:0
作者
Sajadi, S. Mohammad [1 ,2 ,3 ]
机构
[1] Cihan Univ Erbil, Dept Nutr, Erbil, Iraq
[2] Soran Univ, Sci Res Ctr, Soran, Iraq
[3] Soran Univ, Fac Sci, Dept Petr Geosci, POB 624, Soran, Kurdistan Regio, Iraq
关键词
alpha-aminophosphonates; green synthesis; solventless; trialkyl phosphite; ZnO@CuO@Iron ore NCs; ONE-POT SYNTHESIS; AMINO PHOSPHONATES; REUSABLE CATALYST; ACID; INHIBITORS; REDUCTION; ALDEHYDES; REMOVAL; EXTRACT; ANALOGS;
D O I
10.1177/1747519819883883
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A green novel synthesis of ZnO@CuO@Iron ore nanocomposites as a novel and magnetic heterogeneous nanocatalyst is used for the one-pot synthesis of alpha-aminophosphonates under solventless conditions. This study benefits from the magnetic iron ore acting as a multi-mineral Lewis acid system, the green properties and the large surface area due to its nanostructure. Moreover, scanning electron microscope analysis confirmed that the nanocatalyst gave an excellent yield and good recyclability; which, even after the 10th cycle of the model reaction retained its potential with no significant loss of catalytic activity.
引用
收藏
页码:25 / 30
页数:6
相关论文
共 30 条
[1]   RENIN INHIBITORS - SYNTHESIS OF TRANSITION-STATE ANALOG INHIBITORS CONTAINING PHOSPHORUS-ACID DERIVATIVES AT THE SCISSILE BOND [J].
ALLEN, MC ;
FUHRER, W ;
TUCK, B ;
WADE, R ;
WOOD, JM .
JOURNAL OF MEDICINAL CHEMISTRY, 1989, 32 (07) :1652-1661
[2]   Natrolite zeolite: A natural and reusable catalyst for one-pot synthesis of α-aminophosphonates under solvent-free conditions [J].
Bahari, Siavash ;
Sajadi, S. Mohammad .
ARABIAN JOURNAL OF CHEMISTRY, 2017, 10 :S700-S704
[3]   PHOSPHINIC ACID DIPEPTIDE ANALOGS - POTENT, SLOW-BINDING INHIBITORS OF ASPARTIC PEPTIDASES [J].
BARTLETT, PA ;
KEZER, WB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (15) :4282-4283
[4]   A low cost synthesis method for functionalised iron oxide nanoparticles for magnetic hyperthermia from readily available materials [J].
Bear, Joseph C. ;
Yu, Bin ;
Blanco-Andujar, Cristina ;
McNaughter, Paul D. ;
Southern, Paul ;
Mafina, Marc-Krystelle ;
Pankhurst, Quentin A. ;
Parkin, Ivan P. .
FARADAY DISCUSSIONS, 2014, 175 :83-95
[5]   An extremely efficient three-component reaction of aldehydes/ketones, amines, and phosphites (Kabachnik-Fields reaction) for the synthesis of α-aminophosphonates catalyzed by magnesium perchlorate [J].
Bhagat, Srikant ;
Chakraborti, Asit K. .
JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (04) :1263-1270
[6]   An efficient one-pot synthesis of α-amino phosphonates catalyzed by bismuth nitrate pentahydrate [J].
Bhattacharya, Asish K. ;
Kaur, Tanpreet .
SYNLETT, 2007, (05) :745-748
[7]  
Bloemink MJ, 1999, EUR J INORG CHEM, P1655
[8]   Three component coupling catalyzed by TaCl5-SiO2:: synthesis of α-amino phosphonates [J].
Chandrasekhar, S ;
Prakash, SJ ;
Jagadeshwar, V ;
Narsihmulu, C .
TETRAHEDRON LETTERS, 2001, 42 (32) :5561-5563
[9]  
Du S, 1997, BIOORGAN MED CHEM, V7, P2671
[10]   Magnesium triflate [Mg(OTf2] a highly stable, non-hygroscopic and a recyclable catalyst for the high yielding preparation of diethyl α-trimethylsilyloxyphosphonates from diethyl α-hydroxyphosphonates by HMDS under solventless conditions [J].
Firouzabadi, H ;
Iranpoor, N ;
Sobhani, S ;
Ghassamipour, S .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (20) :3197-3202