Bis(pyridine-2-carbaldehyde thiosemicarbazone)zinc(II) dinitrate dihydrate

被引：2
作者：
Cheng, Lin [1 ]
Zhang, Li-Min [1 ]
Wang, Jian-Quan [1 ]
机构：
[1] Southeast Univ, Dept Chem & Chem Engn, Nanjing 211189, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
COMPLEXES;
D O I：
10.1107/S1600536810038614
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, [Zn(C(7)H(8)N(4)S)(2)](NO(3))(2)center dot 2H(2)O, contains two Zn(pht)(2) cations (pht is pyridine-2-carbaldehyde thiosemicarbazone), four nitrate anions and four water molecules. In the cations, each Zn(II) ion adopts a distorted octahedral coordination geometry, being chelated by two tridentate pht ligands. In the crystal, the cations, anions and water molecules are connected via O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds into a three-dimensional network.
引用
收藏
页码：M1340 / U1534
页数：13
相关论文
共 50 条
  • [41] Spin-crossover in iron(ii) coordination compounds with 2,6-bis(benzimidazol-2-yl)pyridine
    Ivanova, A. D.
    Korotaev, E., V
    Komarov, V. Yu
    Sheludyakova, L. A.
    Varnek, V. A.
    Lavrenova, L. G.
    NEW JOURNAL OF CHEMISTRY, 2020, 44 (15) : 5834 - 5840
  • [42] 2-Methylimidazolium pyridine-2,5-dicarboxylato zinc(II) dihydrate: Synthesis, characterization, DNA interaction, anti-microbial, anti-oxidant and anti-breast cancer studies
    Sudha, Dhakshinamoorthy
    Vairam, Sundararajan
    Sarathbabu, Subbarayan
    Kumar, Nachimuthu Senthil
    Sivasamy, Ramasamy
    Kirubavathy, Suyambulingam Jone
    JOURNAL OF COORDINATION CHEMISTRY, 2021, : 2701 - 2719
  • [43] Synthesis and Properties of Iron(II) and Copper(II) Coordination Compounds with 2,6-Bis[1-(phenylimino)ethyl]pyridine
    Lavrenova, L. G.
    Mishchenko, A. A.
    Oleynik, I., V
    Korotaev, E., V
    Lavrov, A. N.
    Grebenkina, M. A.
    Sheludyakova, L. A.
    Klyushova, L. S.
    Oleynik, I. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2021, 91 (11) : 2167 - 2175
  • [44] Synthesis and Characterization of Cobalt(II) and Zinc(II) Coordination Polymers Constructed from Bis(isophthalic acid) and Bis(1,2,4-triazole) Linkers
    Erer, Hakan
    Demir, Sevde
    Karaman, Buse
    Arici, Mursel
    Yesilel, Okan Zafer
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2023, 33 (08) : 2386 - 2398
  • [45] Bis[μ-4-(2-oxidobenzylidene)thiosemicarbazidato-κ4S,N1,O:O]bis[(pyridine-κN)zinc]
    Takjoo, Reza
    Dutkiewicz, Grzegorz
    Ahmadi, Mehdi
    Kubicki, Maciej
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : M106 - U296
  • [46] catena-Poly[bis(4-aminopyridinium) [[tetraaquanickel(II)]-μ-benzene-1,2,4,5-tetracarboxylato] dihydrate]
    Rotondo, Archimede
    Bruno, Giuseppe
    Messina, Fabio
    Nicolo, Francesco
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1203 - +
  • [47] Bis{2-[3-(dimethylamino)propyliminomethyl]-4,6-dihydroselenophenolato}zinc(II)
    Yang, Jun
    Yuan, Ji-Wen
    Zha, Ru-Hua
    Zeng, Qing-Fu
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1090 - U719
  • [48] trans-Bis{2-[(4-hydroxyphenethylimino)-methyl]phenolato}zinc(II) monohydrate
    Xu, Hua-Jie
    Liu, Zhao-Di
    Sheng, Liang-Quan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M2695 - M2697
  • [49] Copper(II) Selective PVC Membrane Based on 3-Doexy-D-erythro-hexos-2-ulose bis(thiosemicarbazone) as a Novel Ionophore
    Masrournia, M.
    Rostame-Faroge, M.
    Behmadi, H.
    ASIAN JOURNAL OF CHEMISTRY, 2010, 22 (06) : 4591 - 4601
  • [50] Crystal structure of aqua-bis(5-bromo-6-methyl-picolinato-κ2N,O)zinc(II) dihydrate, C14H16Br2N2O7Zn
    Li, Jun-Xia
    Du, Zhong-Xiang
    Bai, Ruo-Fei
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2020, 235 (01): : 63 - 65
12345