Bis(pyridine-2-carbaldehyde thiosemicarbazone)zinc(II) dinitrate dihydrate

被引：2
|
作者：
Cheng, Lin [1 ]
Zhang, Li-Min [1 ]
Wang, Jian-Quan [1 ]
机构：
[1] Southeast Univ, Dept Chem & Chem Engn, Nanjing 211189, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
COMPLEXES;
D O I：
10.1107/S1600536810038614
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, [Zn(C(7)H(8)N(4)S)(2)](NO(3))(2)center dot 2H(2)O, contains two Zn(pht)(2) cations (pht is pyridine-2-carbaldehyde thiosemicarbazone), four nitrate anions and four water molecules. In the cations, each Zn(II) ion adopts a distorted octahedral coordination geometry, being chelated by two tridentate pht ligands. In the crystal, the cations, anions and water molecules are connected via O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds into a three-dimensional network.
引用
收藏
页码：M1340 / U1534
页数：13
相关论文
共 50 条
  • [1] Pyridine-2-carbaldehyde thiosemicarbazone
    Song, Li-Hua
    Zhang, Xiang
    Jiang, Kun
    Yang, Sheng-Xiang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O356 - U2451
  • [2] CADMIUM(II) COMPLEXES WITH PYRIDINE-2-CARBALDEHYDE THIOSEMICARBAZONE
    CASAS, JS
    CASTANO, MV
    GARCIA-TASENDE, MS
    MARTINEZ-SANTAMARTA, I
    SORDO, J
    CASTELLANO, EE
    ZUKERMAN-SCHPECTOR, J
    JOURNAL OF CHEMICAL RESEARCH, 1992, (10) : 324 - 325
  • [3] Pyridine-2-carbaldehyde thiosemicarbazone 1.75-hydrate
    Jin, ZM
    Shen, L
    He, L
    Guo, H
    Wang, HT
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : O1909 - O1911
  • [4] Coordinative properties of the pyridine-2-carbaldehyde thiosemicarbazone ligand towards Ni(II)
    C. Graiff
    S. Canossa
    G. Predieri
    Journal of Structural Chemistry, 2014, 55 : 493 - 497
  • [5] Antiviral activity of platinum (II) and palladium (II) complexes of pyridine-2-carbaldehyde thiosemicarbazone
    Varadinova, T
    Kovala-Demertzi, D
    Rupelieva, M
    Demertzis, M
    Genova, P
    ACTA VIROLOGICA, 2001, 45 (02) : 87 - 94
  • [6] Coordinative properties of the pyridine-2-carbaldehyde thiosemicarbazone ligand towards Ni(II)
    Graiff, C.
    Canossa, S.
    Predieri, G.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (03) : 493 - 497
  • [7] DIMETHYLTHALLIUM(III) AND METHYLMERCURY(II) DERIVATIVES OF PYRIDINE-2-CARBALDEHYDE THIOSEMICARBAZONE - SYNTHESIS AND STRUCTURE
    CASAS, JS
    CASTANO, MV
    RODRIGUEZARGUELLES, MC
    SANCHEZ, A
    SORDO, J
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (08): : 1253 - 1259
  • [8] CADMIUM(II) COMPLEXES WITH PYRIDINE-2-CARBALDEHYDE THIOSEMICARBAZONE (MARCH, PG 324, 1992)
    CASAS, JS
    CASTANO, MV
    GARCIATAXENDE, MS
    MARTINEZSANTAMARTA, I
    SANCHEZ, A
    SORDO, J
    CASTELLANO, EE
    ZUKERMANSCHPECTOR, J
    JOURNAL OF CHEMICAL RESEARCH-S, 1993, (03): : 136 - 136
  • [9] Platinum(II) and palladium(II) complexes of pyridine-2-carbaldehyde thiosemicarbazone as alternative antiherpes simplex virus agents
    Kovala-Demertzi, D.
    Varadinova, T.
    Genova, P.
    Souza, P.
    Demertzis, M. A.
    BIOINORGANIC CHEMISTRY AND APPLICATIONS, 2007, 2007
  • [10] Bis(pyridine-2-carbaldehyde thiosemicarbazonato)cobalt(III) perchlorate
    Wang, HS
    Huang, L
    Chen, ZF
    Wang, XW
    Zhou, J
    Shi, SM
    Liang, H
    Yu, KB
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M354 - M356
12345