Pore-controlled formation of 0D metal complexes in anionic 3D metal-organic frameworks

被引：9
作者：
Zhang, Muwei [1 ]
Bosch, Mathieu [1 ]
Zhou, Hong-Cai [1 ,2 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
[2] Texas A&M Univ, Dept Mat Sci & Engn, College Stn, TX 77842 USA
来源：
CRYSTENGCOMM | 2015年 / 17卷 / 05期
关键词：
HOST-GUEST INTERACTIONS; H BOND ACTIVATION; MOLECULAR RECOGNITION; DONOR-ACCEPTOR; CHEMISTRY; ENCAPSULATION; SYSTEMS; DESIGN; FLASKS; SENSOR;
D O I：
10.1039/c4ce02261k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The host-guest chemistry between a series of anionic MOFs and their trapped counterions was investigated by single crystal XRD. The PCN-514 series contains crystallographically identifiable metal complexes trapped in the pores, where their formation is controlled by the size and shape of the MOF pores. A change in the structure and pore size of PCN-518 indicates that the existence of guest molecules may reciprocally affect the formation of host MOFs.
引用
收藏
页码：996 / 1000
页数：5
相关论文
共 50 条
[21]   Poly Tetrazole Containing Thermally Stable and Insensitive Alkali Metal-Based 3D Energetic Metal-Organic Frameworks [J].
Rajak, Richa ;
Kumar, Parasar ;
Ghule, Vikas D. ;
Dharavath, Srinivas .
INORGANIC CHEMISTRY, 2023, 62 (21) :8389-8396
[22]   Two heptanuclear cluster-based 3D metal-organic frameworks with a good magnetocaloric effect [J].
Cao, Shouying ;
Fan, Chenpeng ;
Lu, Mengwen ;
Li, Meng ;
Zhou, Yuhang ;
Wang, Hongxia ;
Lin, Qingfang ;
Liang, Lili .
CRYSTENGCOMM, 2023, 25 (02) :309-313
[23]   Two new 3D lanthanide metal-organic frameworks constructed from nitrilotriacetate and oxalate ligands [J].
Yang, Qing-Feng ;
Cui, Xiao-Bing ;
Chen, Yan ;
Wang, Zheng ;
Yu, Jie-Hui ;
Xu, Ji-Qing ;
Wang, Tie-Gang .
INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (01) :320-323
[24]   Some equivalent two-dimensional weavings at the molecular scale in 2D and 3D metal-organic frameworks [J].
Hyde, Stephen T. ;
Chen, Banglin ;
O'Keeffe, Michael .
CRYSTENGCOMM, 2016, 18 (39) :7607-7613
[25]   Roles of Alkali Metals and Ionic Networks in Directing the Formation of Anionic Metal-Organic Frameworks [J].
Hong, Anh N. ;
Yang, Huajun ;
Zhou, Angel ;
Bu, Xianhui ;
Feng, Pingyun .
CRYSTAL GROWTH & DESIGN, 2020, 20 (10) :6668-6676
[26]   A novel cobalt metal-organic framework with an anionic 3D network built up from two interconnected NbO subnets [J].
Livage, Carine ;
Guillou, Nathalie ;
Castiglione, Andrea ;
Marrot, Jerome ;
Frigoli, Michel ;
Millange, Franck .
MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 157 :37-41
[27]   Chiral recognition of a 3D chiral nanoporous metal-organic framework [J].
Zhang, Mei ;
Pu, Zi-Jie ;
Chen, Xing-Lian ;
Gong, Xiao-Li ;
Zhu, Ai-Xin ;
Yuan, Li-Ming .
CHEMICAL COMMUNICATIONS, 2013, 49 (45) :5201-5203
[28]   An unusual 3D metal-organic framework with multiform helical chains [J].
Liu, Jian-Qiang ;
Wang, Yao-Yu ;
Jia, Zhen-Bin .
INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (04) :519-521
[29]   Guest induced hysteretic tristability in 3D pillared Hofmann-type microporous metal-organic frameworks [J].
Polyzou, C. D. ;
Lalioti, N. ;
Psycharis, V. ;
Tangoulis, V. .
NEW JOURNAL OF CHEMISTRY, 2017, 41 (21) :12384-12387
[30]   Two unprecedented 3D metal-organic polyrotaxane frameworks based on a new flexible tri(imidazole) ligand [J].
Wu, Hua ;
Liu, Hai-Yan ;
Liu, Bo ;
Yang, Jin ;
Liu, Ying-Ying ;
Ma, Jian-Fang ;
Liu, Yun-Yu ;
Bai, Hong-Ye .
CRYSTENGCOMM, 2011, 13 (10) :3402-3407
12345