Pore-controlled formation of 0D metal complexes in anionic 3D metal-organic frameworks

被引：9
|
作者：
Zhang, Muwei [1 ]
Bosch, Mathieu [1 ]
Zhou, Hong-Cai [1 ,2 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
[2] Texas A&M Univ, Dept Mat Sci & Engn, College Stn, TX 77842 USA
来源：
CRYSTENGCOMM | 2015年 / 17卷 / 05期
关键词：
HOST-GUEST INTERACTIONS; H BOND ACTIVATION; MOLECULAR RECOGNITION; DONOR-ACCEPTOR; CHEMISTRY; ENCAPSULATION; SYSTEMS; DESIGN; FLASKS; SENSOR;
D O I：
10.1039/c4ce02261k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The host-guest chemistry between a series of anionic MOFs and their trapped counterions was investigated by single crystal XRD. The PCN-514 series contains crystallographically identifiable metal complexes trapped in the pores, where their formation is controlled by the size and shape of the MOF pores. A change in the structure and pore size of PCN-518 indicates that the existence of guest molecules may reciprocally affect the formation of host MOFs.
引用
收藏
页码：996 / 1000
页数：5
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