Thermal annealing effects on the structural and electrical properties of PMN-PZ-PT ternary thin films deposited by a sol-gel process

被引:6
作者
Shannigrahi, S [1 ]
Yao, K [1 ]
机构
[1] Inst Mat Res & Engn, Singapore 117602, Singapore
关键词
sol-gel process; X-ray methods; dielectric properties; ferroelectric properties; films; PbTiO3;
D O I
10.1016/j.jeurceramsoc.2004.03.030
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Thin film samples of 0.15PMN-0.45PZ-0.40PT (PMN-PZ-PT) three-component system were prepared on Pt-coated Si substrates by a sol-gel process. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), and secondary ion mass spectrometry (SIMS) show that the above films can be formed in a single-phase perovskite structure at 800 degrees C. This was further confirmed by the dielectric and ferroelectric properties of the samples annealed at different temperatures. It was demonstrated that the morphology and microstructures of the PMN-PZ-PT films were quite sensitive to their annealing conditions, which strongly affects their electrical properties. (c) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:759 / 765
页数:7
相关论文
共 23 条
[1]  
Akbas MA, 1996, BRIT CERAM T, V95, P49
[2]  
[Anonymous], POWD INTERACTIVE POW
[3]   Intrinsic piezoelectric response in perovskite alloys: PMN-PT versus PZT [J].
Bellaiche, L ;
Vanderbilt, D .
PHYSICAL REVIEW LETTERS, 1999, 83 (07) :1347-1350
[4]   New piezoceramic PZT-PNN material for medical diagnostics applications [J].
Bove, T ;
Wolny, W ;
Ringgaard, E ;
Pedersen, A .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2001, 21 (10-11) :1469-1472
[5]   Phase development of radio-frequency magnetron sputter-deposited Pb(Mg1/3Nb2/3)O3-PbTiO3 (90/10) thin films [J].
Lee, JK ;
Park, D ;
Cheong, DS ;
Park, JW ;
Park, CS .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 2000, 18 (04) :1659-1662
[6]   Nucleation- or growth-controlled orientation development in chemically derived ferroelectric lead zirconate titanate (Pb(ZrxTi1-x)O-3, x=0.4) thin films [J].
Liu, YM ;
Phule, PP .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1996, 79 (02) :495-498
[7]  
Miyashita S., 2000, US Patent, Patent No. [6 140 746, 6140746]
[8]  
MOULSON AJ, 1990, ELECTROCERAMIC
[9]   Role of substrate on the dielectric and piezoelectric behavior of epitaxial lead magnesium niobate-lead titanate relaxor thin films [J].
Nagarajan, V ;
Alpay, SP ;
Ganpule, CS ;
Nagaraj, BK ;
Aggarwal, S ;
Williams, ED ;
Roytburd, AL ;
Ramesh, R .
APPLIED PHYSICS LETTERS, 2000, 77 (03) :438-440
[10]   Role of fluorite phase formation in the texture selection of sol-gel-prepared Pb(Zr1-x,Tix)O3 films on Pt electrode layers [J].
Norga, GJ ;
Vasiliu, F ;
Fè, L ;
Wouters, DJ ;
Van der Biest, O .
JOURNAL OF MATERIALS RESEARCH, 2003, 18 (05) :1232-1238