Fabrication and Characterization of Electrospun Nanofibers of High DP Natural Cotton Lines Cellulose

被引:17
作者
Li, Chaorong [1 ]
Chen, Rui
Zhang, Xiaoqiang
Xiong, Jie
Zheng, Yingying
Dong, Wenjun
机构
[1] Zhejiang Sci Tech Univ, Dept Phys, Ctr Optoelect Mat, Minist Educ, Hangzhou 310018, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Electrospinning; Cotton lines cellulose; Nonwoven; Oriented; Wettability; SOLVENT EXCHANGE; FIBERS; DISSOLUTION; BEHAVIOR; TEMPERATURE; SYSTEM;
D O I
10.1007/s12221-011-0345-4
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
Nanofibers of natural cotton lines cellulose, with a degree of polymerization above 10000, were prepared by electrospinning. The effects of cellulose concentration, flow rate and electric field strength on the morphologies of the fibers were systematically investigated. Furthermore, two effective improvements on the electrospinning apparatus were made: heating the pathway between the tip of the needle and the collector instead of the needle or the collector, and covering the drum with activated cellulose flake. High quality cellulose nanofibers were obtained under the optimized spinning conditions combined with the apparatus improvements. Moreover, oriented cotton nanofibers were acquired by elevating the rotation speed of the drum collector. The wettability of the nonwoven was greatly improved compared with the original activated cellulose. The obtained nonwoven or nanofibers of the natural cotton cellulose could be potentially applied in tissue scaffolds, protective clothing and high efficient water absorbing materials etc.
引用
收藏
页码:345 / 351
页数:7
相关论文
共 26 条
  • [1] The investigation of the influence of water and temperature on the LiCl/DMAc/cellulose system
    Chrapava, S
    Touraud, D
    Rosenau, T
    Potthast, A
    Kunz, W
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (09) : 1842 - 1847
  • [2] Cellulose in lithium chloride/N,N-dimethylacetamide, optimisation of a dissolution method using paper substrates and stability of the solutions
    Dupont, AL
    [J]. POLYMER, 2003, 44 (15) : 4117 - 4126
  • [3] NANOCOMPOSITE MATERIALS FROM LATEX AND CELLULOSE WHISKERS
    FAVIER, V
    CANOVA, GR
    CAVAILLE, JY
    CHANZY, H
    DUFRESNE, A
    GAUTHIER, C
    [J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 1995, 6 (05) : 351 - 355
  • [4] Fabrication of aligned and molecularly oriented electrospun polyacrylonitrile nanofibers and the mechanical behavior of their twisted yams
    Fennessey, SF
    Farris, RJ
    [J]. POLYMER, 2004, 45 (12) : 4217 - 4225
  • [5] Electrospinning cellulose and cellulose derivatives
    Frey, Margaret W.
    [J]. POLYMER REVIEWS, 2008, 48 (02) : 378 - 391
  • [6] Electrospinning of ultrafine cellulose fibers and fabrication of poly(butylene succinate) biocomposites reinforced by them
    Han, Seong Ok
    Son, Won Keun
    Youk, Ji Ho
    Park, Won Ho
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 107 (03) : 1954 - 1959
  • [7] A review on polymer nanofibers by electrospinning and their applications in nanocomposites
    Huang, ZM
    Zhang, YZ
    Kotaki, M
    Ramakrishna, S
    [J]. COMPOSITES SCIENCE AND TECHNOLOGY, 2003, 63 (15) : 2223 - 2253
  • [8] Effect of solvent exchange on the solid structure and dissolution behavior of cellulose
    Ishii, D
    Tatsumi, D
    Matsumoto, T
    [J]. BIOMACROMOLECULES, 2003, 4 (05) : 1238 - 1243
  • [9] The residual amide content of cellulose sequentially solvent-exchanged and then vacuum-dried
    Ishii, Daisuke
    Isogai, Akira
    [J]. CELLULOSE, 2008, 15 (04) : 547 - 553
  • [10] Preparation of electrospun oxidized cellulose mats and their in vitro degradation behavior
    Khil, MS
    Kim, HY
    Kang, YS
    Bang, HJ
    Lee, DR
    Doo, JK
    [J]. MACROMOLECULAR RESEARCH, 2005, 13 (01) : 62 - 67